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231226s2023 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.3c00120
|2 doi
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|a pubmed24n1180.xml
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|a (DE-627)NLM354255363
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|a (NLM)36919992
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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| 100 |
1 |
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|a Chen, Zhenghao
|e verfasserin
|4 aut
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|a AC-Bipolar Electropolymerization of 3,4-Ethylenedioxythiophene in Ionic Liquids
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|c 2023
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 28.03.2023
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|a Date Revised 01.04.2023
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Recently, alternating current (AC)-bipolar electropolymerization of 3,4-ethylenedioxythiophene (EDOT) has been reported to produce poly(3,4-ethylenedioxythiophene) (PEDOT) fibers from the terminals of bipolar electrodes in acetonitrile solution (MeCN) containing low concentrations of supporting salts in a template-free manner. Here, we extend such methodology in ionic liquid (IL) media. Three kinds of ILs, diethylmethyl(2-methoxyethyl)ammonium tetrafluoroborate ([DEME][BF4]), 1-ethyl-3-methylimidazolium tetrafluoroborate ([EMIM][BF4]), and diethylmethyl(2-methoxyethyl)ammonium bis(trifluoromethylsulfonyl)imide ([DEME][TFSI]), with different electric field transmission efficiencies and diffusion coefficients were employed as solvents for the AC-bipolar electropolymerization of EDOT. A variety of PEDOT morphologies were obtained in these three ILs, showing a relationship with the physicochemical properties of the ILs. We successfully confirmed the growth of PEDOT fibers in ILs and systematically discussed the factors that influenced their growth
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|a Journal Article
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1 |
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|a Zhou, Yaqian
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Villani, Elena
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Shida, Naoki
|e verfasserin
|4 aut
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1 |
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|a Tomita, Ikuyoshi
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Inagi, Shinsuke
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1999
|g 39(2023), 12 vom: 28. März, Seite 4450-4455
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:39
|g year:2023
|g number:12
|g day:28
|g month:03
|g pages:4450-4455
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|u http://dx.doi.org/10.1021/acs.langmuir.3c00120
|3 Volltext
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