Thermally Enhanced and Long Lifetime Red TADF Carbon Dots via Multi-Confinement and Phosphorescence Assisted Energy Transfer
© 2023 Wiley-VCH GmbH.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 35(2023), 20 vom: 24. Mai, Seite e2211858 |
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| Weitere Verfasser: | , , , , , , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2023
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| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article TADF carbon dot energy transfer thermally enhanced luminescence time-/temperature-dependent delayed emission |
| Zusammenfassung: | © 2023 Wiley-VCH GmbH. Thermally activated delayed fluorescence (TADF) materials, which can harvest both singlet and triplet excitons for high-efficiency emission, have attracted widespread concern for their enormous applications. Nevertheless, luminescence thermal quenching severely limits the efficiency and operating stability in TADF materials and devices at high temperature. Herein, a surface engineering strategy is adopted to obtain unique carbon dots (CDs)-based thermally enhanced TADF materials with ≈250% enhancement from 273 to 343 K via incorporating seed CDs into ionic crystal network. The rigid crystal network can simultaneously boost reverse intersystem crossing process via enhancing spin-orbit coupling between singlet and triplet states and suppressing non-radiative transition rate, contributing to the thermally enhanced TADF character. Benefiting from efficient energy transfer from triplet states of phosphorescence center to singlet states of CDs, TADF emission at ≈600 nm in CDs displays a long lifetime up to 109.6 ms, outperforming other red organic TADF materials. Thanks to variable decay rates of the delayed emission centers, time and temperature-dependent delayed emission color has been first realized in CDs-based delayed emission materials. The CDs with thermally enhanced and time-/temperature-dependent emission in one material system can offer new opportunities in information protection and processing |
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| Beschreibung: | Date Completed 18.05.2023 Date Revised 18.05.2023 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.202211858 |