Swelling-Activated, Soft Mechanochemistry in Polymer Materials

Swelling in polymer materials is a ubiquitous phenomenon. At a molecular level, swelling is dictated by solvent-polymer interactions, and has been thoroughly studied both theoretically and experimentally. Favorable solvent-polymer interactions result in the solvation of polymer chains. For polymers...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 39(2023), 10 vom: 14. März, Seite 3546-3557
1. Verfasser: Metze, Friederike Katharina (VerfasserIn)
Weitere Verfasser: Sant, Sabrina, Meng, Zhao, Klok, Harm-Anton, Kaur, Kuljeet
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2023
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Review
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520 |a Swelling in polymer materials is a ubiquitous phenomenon. At a molecular level, swelling is dictated by solvent-polymer interactions, and has been thoroughly studied both theoretically and experimentally. Favorable solvent-polymer interactions result in the solvation of polymer chains. For polymers in confined geometries, such as those that are tethered to surfaces, or for polymer networks, solvation can lead to swelling-induced tensions. These tensions act on polymer chains and can lead to stretching, bending, or deformation of the material both at the micro- and macroscopic scale. This Invited Feature Article sheds light on such swelling-induced mechanochemical phenomena in polymer materials across dimensions, and discusses approaches to visualize and characterize these effects 
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700 1 |a Meng, Zhao  |e verfasserin  |4 aut 
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700 1 |a Kaur, Kuljeet  |e verfasserin  |4 aut 
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