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231226s2023 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202300982
|2 doi
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|a pubmed24n1177.xml
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|a DE-627
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|e rakwb
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|a eng
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|a Chen, Yong
|e verfasserin
|4 aut
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|a Durable and Adjustable Interfacial Engineering of Polymeric Electrolytes for Both Stable Ni-Rich Cathodes and High-Energy Metal Anodes
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|c 2023
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 07.05.2023
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|a Date Revised 07.05.2023
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2023 Wiley-VCH GmbH.
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|a Achieving stable cycling of high-voltage solid-state lithium metal batteries is crucial for next-generation rechargeable batteries with high energy density and high safety. However, the complicated interface problems in both cathode/anode electrodes preclude their practical applications hitherto. Herein, to simultaneously solve such interfacial limitations and obtain sufficient Li+ conductivity in the electrolyte, an ultrathin and adjustable interface is developed at the cathode side through a convenient surface in situ polymerization (SIP), achieving a durable high-voltage tolerance and Li-dendrite inhibition. The integrated interfacial engineering fabricates a homogeneous solid electrolyte with optimized interfacial interactions that contributes to tame the interfacial compatibility between LiNix Coy Mnz O2 and polymeric electrolyte accompanied by anticorrosion of aluminum current collector. Further, the SIP enables a uniform adjustment of solid electrolyte composition by dissolving additives such as Na+ and K+ salts, which presents prominent cyclability in symmetric Li cells (>300 cycles at 5 mA cm-2 ). The assembled LiNi0.8 Co0.1 Mn0.1 O2 (4.3 V)||Li batteries show excellent cycle life with high Coulombic efficiencies (>99%). This SIP strategy is also investigated and verified in sodium metal batteries. It opens a new frontier for solid electrolytes toward high-voltage and high-energy metal battery technologies
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|a Journal Article
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|a high voltage
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|a metal anode
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|a solid polymeric electrolyte
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|a surface in situ polymerization
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|a Cui, Yingyue
|e verfasserin
|4 aut
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|a Wang, Simeng
|e verfasserin
|4 aut
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|a Xiao, Ying
|e verfasserin
|4 aut
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|a Niu, Jin
|e verfasserin
|4 aut
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|a Huang, Jiajia
|e verfasserin
|4 aut
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|a Wang, Feng
|e verfasserin
|4 aut
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|a Chen, Shimou
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 35(2023), 18 vom: 20. Mai, Seite e2300982
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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|g volume:35
|g year:2023
|g number:18
|g day:20
|g month:05
|g pages:e2300982
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|u http://dx.doi.org/10.1002/adma.202300982
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