Adsorptive removal of Cr(III)-EDTA chelate from an aqueous solution by magnetic mesoporous silica microspheres
The 3-aminopropyltrimethoxysilane-modified magnetic mesoporous adsorbent (FNMs/APTES) was synthesized and applied to remove Cr(III)-EDTA chelates from water. The characterization of FNMs/APTES showed that the prepared adsorbent with a magnetic mesoporous structure was successfully grafted by APTES,...
| Veröffentlicht in: | Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 87(2023), 3 vom: 01. Feb., Seite 571-583 |
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| Weitere Verfasser: | , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2023
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| Zugriff auf das übergeordnete Werk: | Water science and technology : a journal of the International Association on Water Pollution Research |
| Schlagworte: | Journal Article Silicon Dioxide 7631-86-9 Edetic Acid 9G34HU7RV0 Water 059QF0KO0R Chelating Agents Indicators and Reagents Water Pollutants, Chemical |
| Zusammenfassung: | The 3-aminopropyltrimethoxysilane-modified magnetic mesoporous adsorbent (FNMs/APTES) was synthesized and applied to remove Cr(III)-EDTA chelates from water. The characterization of FNMs/APTES showed that the prepared adsorbent with a magnetic mesoporous structure was successfully grafted by APTES, which has good stability under acid conditions. The maximum capacities of FNMs/APTES for Cr(III)-EDTA adsorption at 15, 25 and 35 °C and pH 4.0 were 12.58, 13.13 and 14.00 mg·g-1, respectively. The adsorption isotherm of FNMs/APTES for Cr(III)-EDTA conforms to the Freundlich model, and the adsorption kinetic model accords with the pseudo-second-order kinetic model. Adsorption of Cr(III)-EDTA on the adsorbent was not affected in the presence of Na+, K+ and Ca2+ even at 100 mmol·L-1. Cr(III)-EDTA was anchored on FNMs/APTES through electrostatic interaction between protonated amino groups of adsorbents and Cr(III)-EDTA anions, and Cr(III)-EDTA chelates were adsorbed as a whole on the adsorbent. The Cr(III)-EDTA-saturated adsorbent can be readily regenerated in HCl solution and 83.03% of the initial Cr(III)-EDTA adsorption capacity remains after four adsorption-regeneration experiment cycles. The results highlighted that the FNMs/APTES as a potential adsorbent can be applied for the minimization of Cr(III)-EDTA chelates from water |
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| Beschreibung: | Date Completed 16.02.2023 Date Revised 16.02.2023 published: Print Citation Status MEDLINE |
| ISSN: | 0273-1223 |
| DOI: | 10.2166/wst.2023.011 |