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231226s2023 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202210693
|2 doi
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|a pubmed24n1175.xml
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|a eng
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|a Tang, Zheng
|e verfasserin
|4 aut
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|a Reaction Site Designation by Intramolecular Electric Field in Tröger's-Base-Derived Conjugated Microporous Polymer for Near-Unity Selectivity of CO2 Photoconversion
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|c 2023
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|a Text
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|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 16.05.2023
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|a Date Revised 16.05.2023
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2023 Wiley-VCH GmbH.
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|a To facilitate solar-driven overall CO2 and H2 O convsersion into fuels and O2 , a series of covalent microporous polymers derived from Tröger's base are synthesized featuring flexural backbone and unusual charge-transfer properties. The incorporation of rigid structural twist Tröger's base unit grants the polymers enhanced microporosity and CO2 adsorption/activation capacity. Density function theory calculations and photo-electrochemical analyses reveal that an electric dipole moment (from negative to positive) directed to the Tröger's base unit is formed across two obliquely opposed molecular fragments and induces an intramolecular electric field. The Tröger's base unit located at folding point becomes an electron trap to attract photogenerated electrons in the molecular network, which brings about suppression of carrier recombination and designates the reaction site in synergy with the conjugated network. In response to the discrepancy in reaction pathways across the reaction sites, the product allocation in the catalytic reaction is thereby regulated. Optimally, CMP-nTB achieves the highest photocatalytic CO production of 163.53 µmol g-1 h-1 with approximately unity selectivity, along with H2 O oxidation to O2 in the absence of any photosensitizer or co-catalyst. This work provides new insight for developing specialized artificial organic photocatalysts
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|a Journal Article
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|a CO2 conversion
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|a Tröger's base
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|a covalent microporous polymers
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|a intramolecular electric fields
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|a photocatalysis
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|a Xu, Shengyu
|e verfasserin
|4 aut
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|a Yin, Nan
|e verfasserin
|4 aut
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|a Yang, Yong
|e verfasserin
|4 aut
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|a Deng, Qinghua
|e verfasserin
|4 aut
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|a Shen, Jinyou
|e verfasserin
|4 aut
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|a Zhang, Xiaoyue
|e verfasserin
|4 aut
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|a Wang, Tianyu
|e verfasserin
|4 aut
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|a He, Huichao
|e verfasserin
|4 aut
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|a Lin, Xiangyang
|e verfasserin
|4 aut
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|a Zhou, Yong
|e verfasserin
|4 aut
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|a Zou, Zhigang
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 35(2023), 17 vom: 10. Apr., Seite e2210693
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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|g volume:35
|g year:2023
|g number:17
|g day:10
|g month:04
|g pages:e2210693
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|u http://dx.doi.org/10.1002/adma.202210693
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