Zn(II) removal from wastewater by an alkali-activated material prepared from steel industry slags : optimization and modelling of a fixed-bed process

Removal of dissolved zinc (Zn) from water by a novel alkali-activated material (AAM) prepared from steel industry slags in a fixed-bed column was investigated. Design of experiments was used to find the optimum operation parameters [flow rate (Q), adsorbent mass, (mads), and initial Zn concentration...

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Veröffentlicht in:Environmental technology. - 1993. - 45(2024), 13 vom: 09. Mai, Seite 2519-2530
1. Verfasser: Manninen, Mikael (VerfasserIn)
Weitere Verfasser: Kangas, Teija, Hu, Tao, Varila, Toni, Lassi, Ulla, Runtti, Hanna
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Journal Article Alkali-activated materials breakthrough curve modelling design of experiments fixed-bed column water treatment Zinc J41CSQ7QDS Wastewater Water Pollutants, Chemical mehr... Steel 12597-69-2 Industrial Waste Alkalies
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520 |a Removal of dissolved zinc (Zn) from water by a novel alkali-activated material (AAM) prepared from steel industry slags in a fixed-bed column was investigated. Design of experiments was used to find the optimum operation parameters [flow rate (Q), adsorbent mass, (mads), and initial Zn concentration (C0)] for the removal of Zn2+ from a ZnCl2 solution. Regression models for the breakthrough (qb), and saturation (qsat) capacities of the bed and three other response parameters as functions of Q, mads and C0 were fitted with coefficients of determination (R2) ranging from 0.48 to 0.99. Experimental values of qb and qsat varied within 1.42-7.03 mg Zn/g and 10.57-17.25 mg Zn/g, respectively. The optimum operation parameters were determined to be Q= 1.64 ml/min and mads= 4.5 g, whereas C0 had negligible effect on the response parameters in the range 73-107 mg Zn/l. Finally, three empirical breakthrough curve (BTC) models were employed to describe the individual BTCs of which the modified dose - response model was found to give the best fit (0.960 ≤ R2 ≤ 0.998). The results of the present work demonstrate that the novel AAM has considerable potential to be utilized in water purification applications 
650 4 |a Journal Article 
650 4 |a Alkali-activated materials 
650 4 |a breakthrough curve modelling 
650 4 |a design of experiments 
650 4 |a fixed-bed column 
650 4 |a water treatment 
650 7 |a Zinc  |2 NLM 
650 7 |a J41CSQ7QDS  |2 NLM 
650 7 |a Wastewater  |2 NLM 
650 7 |a Water Pollutants, Chemical  |2 NLM 
650 7 |a Steel  |2 NLM 
650 7 |a 12597-69-2  |2 NLM 
650 7 |a Industrial Waste  |2 NLM 
650 7 |a Alkalies  |2 NLM 
700 1 |a Kangas, Teija  |e verfasserin  |4 aut 
700 1 |a Hu, Tao  |e verfasserin  |4 aut 
700 1 |a Varila, Toni  |e verfasserin  |4 aut 
700 1 |a Lassi, Ulla  |e verfasserin  |4 aut 
700 1 |a Runtti, Hanna  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Environmental technology  |d 1993  |g 45(2024), 13 vom: 09. Mai, Seite 2519-2530  |w (DE-627)NLM098202545  |x 1479-487X  |7 nnas 
773 1 8 |g volume:45  |g year:2024  |g number:13  |g day:09  |g month:05  |g pages:2519-2530 
856 4 0 |u http://dx.doi.org/10.1080/09593330.2023.2177565  |3 Volltext 
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