Superior adsorption and removal of industrial dye from aqueous solution via magnetic silver metal-organic framework nanocomposite

The indirect emission had a negative influence on the ecosystem of enormous amounts of harmful dyes into water. Fe3O4Ag-MOF was successfully fabricated to capture Gentine violet (GV)) as a model example of cationic dye from their aqueous solutions was evaluated in this search as a method to eliminat...

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Détails bibliographiques
Publié dans:Environmental technology. - 1993. - 45(2024), 13 vom: 16. Mai, Seite 2558-2574
Auteur principal: Mogharbel, Roaa T (Auteur)
Autres auteurs: Alkhamis, Kholood, Felaly, Rasha, El-Desouky, M G, El-Bindary, A A, El-Metwaly, Nashwa M, El-Bindary, M A
Format: Article en ligne
Langue:English
Publié: 2024
Accès à la collection:Environmental technology
Sujets:Journal Article Fe3O4@Ag-MOF gentine violet removal reusability waste water Water Pollutants, Chemical Coloring Agents Metal-Organic Frameworks Silver plus... 3M4G523W1G Gentian Violet J4Z741D6O5
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520 |a The indirect emission had a negative influence on the ecosystem of enormous amounts of harmful dyes into water. Fe3O4Ag-MOF was successfully fabricated to capture Gentine violet (GV)) as a model example of cationic dye from their aqueous solutions was evaluated in this search as a method to eliminate dyes from water contaminants. FTIR, XPS, BET, TGA, SEM, TEM, and XRD have all been used to study this adsorbent in order to determine its structural and chemical characteristics as well as to interpret its binding mechanisms. According to the results of the characterization, the synthesized composite had a size about 45 nm, a surface area of 856.06 m2/g, and considerable magnetic characteristics (66.2 emug-1). Consequently, we created mesoporous surfaces that had a strong ability to interface and absorb GV dye. It is possible to use the pseudo-second order rate equation to characterize the kinetic profile., while the Langmuir equation fits isotherm models. At pH 9, maximum sorption capacities can reach 1.68 mmol.g-1. Additionally, the investigations of temperature profiles indicated the endothermic process and Thermodynamic parameters were discovered as, ΔG°, ΔH° and ΔS° The synthesized adsorbent had an interestingly high reusability of > 92 percent up to the sixth cycle. These findings revealed that a mixture of electrostatic interactions, π-π stacking, hydrogen bonds, and pore filling were involved in the GV adsorption mechanism. Fe3O4@Ag-MOF was successful in demonstrating its effectiveness as a point-of-use colour collection candidate from actual dyeing effluents 
650 4 |a Journal Article 
650 4 |a Fe3O4@Ag-MOF 
650 4 |a gentine violet 
650 4 |a removal 
650 4 |a reusability 
650 4 |a waste water 
650 7 |a Water Pollutants, Chemical  |2 NLM 
650 7 |a Coloring Agents  |2 NLM 
650 7 |a Metal-Organic Frameworks  |2 NLM 
650 7 |a Silver  |2 NLM 
650 7 |a 3M4G523W1G  |2 NLM 
650 7 |a Gentian Violet  |2 NLM 
650 7 |a J4Z741D6O5  |2 NLM 
700 1 |a Alkhamis, Kholood  |e verfasserin  |4 aut 
700 1 |a Felaly, Rasha  |e verfasserin  |4 aut 
700 1 |a El-Desouky, M G  |e verfasserin  |4 aut 
700 1 |a El-Bindary, A A  |e verfasserin  |4 aut 
700 1 |a El-Metwaly, Nashwa M  |e verfasserin  |4 aut 
700 1 |a El-Bindary, M A  |e verfasserin  |4 aut 
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773 1 8 |g volume:45  |g year:2024  |g number:13  |g day:16  |g month:05  |g pages:2558-2574 
856 4 0 |u http://dx.doi.org/10.1080/09593330.2023.2178331  |3 Volltext 
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