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231226s2023 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202211203
|2 doi
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|a pubmed24n1173.xml
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|a (DE-627)NLM352153180
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|a (NLM)36704837
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Qing, Piao
|e verfasserin
|4 aut
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|a Highly Reversible Lithium Metal Anode Enabled by 3D Lithiophilic-Lithiophobic Dual-Skeletons
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|c 2023
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 13.04.2023
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|a Date Revised 13.04.2023
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2023 Wiley-VCH GmbH.
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|a Lithium metal is a promising anode for high-energy-density lithium batteries, but its practical application is still hindered by intrinsic defects such as infinite volume expansion and uncontrollable dendrite growth. Herein, a dendrite-free 3D composite Li anode (Li-BSSM) is prepared by mechanical rolling of lithiophilic LiB nanofibers supported by Li-B composite and lithiophobic stainless-steel mesh (SSM). Featuring hierarchical lithiophilic-lithiophobic dual-skeletons, the Li-B@SSM anode shows an ultrahigh Coulombic efficiency of 99.95% and a long lifespan of 900 h under 2 mA cm-2 /1 mAh cm-2 . It is demonstrated that the abnormally reversible Li stripping/plating processes should be closely related to the site-selective plating behavior and spatial confinement effect induced by the robust lithiophilic-lithiophobic dual-skeletons, which alleviates the volume changes, suppresses the growth of Li dendrites, and reduces the accumulation of "dead" Li. More importantly, the application feasibility of the Li-B@SSM anode is also confirmed in full batteries, of which the Li-B@SSM|LiFePO4 full cell shows a high capacity retention of 97.5% after 400 cycles while the Li-B@SSM|S pouch battery exhibits good cycle stability even under practically harsh conditions. This work paves the way for the facile and efficient fabrication of high-efficiency Li metal anodes toward practical applications
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|a Journal Article
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|a Li-B alloys
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|a dual-skeletons
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|a high CE
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|a lithium metal anodes
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|a selective deposition
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|a Wu, Zhibin
|e verfasserin
|4 aut
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|a Wang, Anbang
|e verfasserin
|4 aut
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|a Huang, Shaozhen
|e verfasserin
|4 aut
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|a Long, Kecheng
|e verfasserin
|4 aut
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|a Naren, Tuoya
|e verfasserin
|4 aut
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|a Chen, Dongping
|e verfasserin
|4 aut
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|a He, Pan
|e verfasserin
|4 aut
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|a Huang, Haifeng
|e verfasserin
|4 aut
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|a Chen, Yuejiao
|e verfasserin
|4 aut
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|a Mei, Lin
|e verfasserin
|4 aut
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| 700 |
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|a Chen, Libao
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 35(2023), 15 vom: 26. Apr., Seite e2211203
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
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|g volume:35
|g year:2023
|g number:15
|g day:26
|g month:04
|g pages:e2211203
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|u http://dx.doi.org/10.1002/adma.202211203
|3 Volltext
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