|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM352003804 |
| 003 |
DE-627 |
| 005 |
20231226052731.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231226s2023 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/acs.langmuir.2c03008
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1173.xml
|
| 035 |
|
|
|a (DE-627)NLM352003804
|
| 035 |
|
|
|a (NLM)36689688
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Meng, Ke-Juan
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Graphene Oxide-Intercalated Tetrazole-Based Coordination Polymers
|b Thermally Stable Hybrid Energetic Crystals with Enhanced Photosensitivity
|
| 264 |
|
1 |
|c 2023
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 07.02.2023
|
| 500 |
|
|
|a Date Revised 07.02.2023
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a High-energy-density photosensitive pyrotechnics with good thermal stability have been in increasing demand in recent years. In this paper, graphene oxide (GO)-intercalated energetic coordination polymers (ECPs) are prepared with improved thermostability but great photosensitivity by using high nitrogen compounds azotetrazole (AT) and 5,5'-bistetrazole-1,1'-diolate dehydrate (BTO) as ligands. The decomposition activation energy (Ea) of Cu-AT has been increased from 135.7 to 151.9 kJ·mol-1 after intercalating 5 wt% GO, and in the meantime, the exothermic peak temperature (Tp) was increased by 12.6 °C. However, the decomposition Ea of Cu-BTO decreased under the effect of the same amount of GO with little effect on Tp. This confirms that GO has stabilization effects on the Cu-AT crystal, whereas the catalytic effects on Cu-BTO would dominate after dehydration with its crystal lattice collapse. Also, when the content of GO was 3%, the resultant GO0.03-Cu-AT exhibits a higher density (2.88 g·cm-3) and good thermostability (Tp = 293.7 °C). This ECP shows excellent low-energy laser ignition performance, which can be ignited with an energy of less than 1 mJ at a wavelength of 976 nm. Low-energy laser initiation is considered to be a safer but more reliable method than the traditional electrical-based ones
|
| 650 |
|
4 |
|a Journal Article
|
| 700 |
1 |
|
|a Yang, Sulan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yu, Minghui
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Lu, Feipeng
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a He, Aifeng
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yan, Qi-Long
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 39(2023), 5 vom: 07. Feb., Seite 1957-1967
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
|
| 773 |
1 |
8 |
|g volume:39
|g year:2023
|g number:5
|g day:07
|g month:02
|g pages:1957-1967
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/acs.langmuir.2c03008
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_22
|
| 912 |
|
|
|a GBV_ILN_350
|
| 912 |
|
|
|a GBV_ILN_721
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 39
|j 2023
|e 5
|b 07
|c 02
|h 1957-1967
|