Sequential Deposition of Multicomponent Bulk Heterojunctions Increases Efficiency of Organic Solar Cells

© 2023 Wiley-VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 35(2023), 12 vom: 17. März, Seite e2208997
1. Verfasser: Xu, Xiaopeng (VerfasserIn)
Weitere Verfasser: Jing, Wenwen, Meng, Huifeng, Guo, Yuanyuan, Yu, Liyang, Li, Ruipeng, Peng, Qiang
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2023
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article morphology control multicomponent bulk heterojunctions nonfullerene organic solar cells sequential deposition vertical phase separation
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520 |a Constructing tandem and multi-blend organic solar cells (OSCs) is an effective way to overcome the absorption limitations of conventional single-junction devices. However, these methods inevitably require tedious multilayer deposition or complicated morphology-optimization procedures. Herein, sequential deposition is utilized as an effective and simple method to fabricate multicomponent OSCs with a double-bulk heterojunction (BHJ) structure of the active layer to further improve photovoltaic performance. Two efficient donor-acceptor pairs, D18-Cl:BTP-eC9 and PM6:L8-BO, are sequentially deposited to form the D18-Cl:BTP-eC9/PM6:L8-BO double-BHJ active layer. In these double-BHJ OSCs, light absorption is significantly improved, and optimal morphology is also retained without requiring a more complicated morphology optimization involved in quaternary blends. Compared to the quaternary blend devices, energy loss (Eloss ) is also reduced by rationally matching each donor with an appropriate acceptor. Consequently, the power conversion efficiency (PCE) is improved from 18.25% for D18-Cl:BTP-eC9 and 18.69% for PM6:L8-BO based binary blend OSCs to 19.61% for the double-BHJ OSCs. In contrast, a D18-Cl:PM6:L8-BO:BTP-eC9 quaternary blend of OSCs exhibited a dramatically reduced PCE of 15.83%. These results demonstrate that a double-BHJ strategy, with a relatively simple processing procedure, can potentially enhance the device performance of OSCs and lead to more widespread use 
650 4 |a Journal Article 
650 4 |a morphology control 
650 4 |a multicomponent bulk heterojunctions 
650 4 |a nonfullerene organic solar cells 
650 4 |a sequential deposition 
650 4 |a vertical phase separation 
700 1 |a Jing, Wenwen  |e verfasserin  |4 aut 
700 1 |a Meng, Huifeng  |e verfasserin  |4 aut 
700 1 |a Guo, Yuanyuan  |e verfasserin  |4 aut 
700 1 |a Yu, Liyang  |e verfasserin  |4 aut 
700 1 |a Li, Ruipeng  |e verfasserin  |4 aut 
700 1 |a Peng, Qiang  |e verfasserin  |4 aut 
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773 1 8 |g volume:35  |g year:2023  |g number:12  |g day:17  |g month:03  |g pages:e2208997 
856 4 0 |u http://dx.doi.org/10.1002/adma.202208997  |3 Volltext 
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