|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM351500790 |
| 003 |
DE-627 |
| 005 |
20231226051520.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231226s2023 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202208951
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1171.xml
|
| 035 |
|
|
|a (DE-627)NLM351500790
|
| 035 |
|
|
|a (NLM)36639140
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Biao, Jie
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Inhibiting Formation and Reduction of Li2 CO3 to LiCx at Grain Boundaries in Garnet Electrolytes to Prevent Li Penetration
|
| 264 |
|
1 |
|c 2023
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 23.03.2023
|
| 500 |
|
|
|a Date Revised 23.03.2023
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2023 Wiley-VCH GmbH.
|
| 520 |
|
|
|a Poor ion and high electron transport at the grain boundaries (GBs) of ceramic electrolytes are the primary reasons for lithium filament infiltration and short-circuiting of all-solid-state lithium metal batteries (ASLMBs). Herein, it is discovered that Li2 CO3 at the GBs of Li7 La3 Zr2 O12 (LLZO) sheets is reduced to highly electron-conductive LiCx during cycling, resulting in lithium penetration of LLZO. The ionic and electronic conductivity of the GBs within LLZO can be simultaneously tuned using sintered Li3 AlF6 . The generated LiAlO2 (LAO) infusion and F-doping at the GBs of LLZO (LAO-LLZOF) significantly reduce the Li2 CO3 content and broaden the energy bandgap of LLZO, which decreases the electronic conductivity of LAO-LLZOF. LAO forms a 3D continuous ion transport network at the GB that significantly improves the total ionic conductivity. Lithium penetration within LLZO is suppressed and an all-solid-state LiFePO4 /LAO-LLZOF/Li battery stably cycled for 5500 cycles at 3 C. This work reveals the chemistry of Li2 CO3 at the LLZO GBs during cycling, presents a novel lithium penetration mechanism within garnet electrolytes, and provides an innovative method to simultaneously regulate the ion and electron transport at the GBs in garnet electrodes for advanced ASLMBs
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a LLZO grain boundary
|
| 650 |
|
4 |
|a Li2CO3
|
| 650 |
|
4 |
|a Lithium penetration mechanism
|
| 650 |
|
4 |
|a ion/electron transport
|
| 700 |
1 |
|
|a Han, Bing
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Cao, Yidan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Li, Qidong
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhong, Guiming
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Ma, Jiabin
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Chen, Likun
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yang, Ke
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Mi, Jinshuo
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Deng, Yonghong
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Liu, Ming
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Lv, Wei
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Kang, Feiyu
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a He, Yan-Bing
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 35(2023), 12 vom: 13. März, Seite e2208951
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:35
|g year:2023
|g number:12
|g day:13
|g month:03
|g pages:e2208951
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202208951
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 35
|j 2023
|e 12
|b 13
|c 03
|h e2208951
|