|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM351452311 |
| 003 |
DE-627 |
| 005 |
20231226051412.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231226s2023 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202209140
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1171.xml
|
| 035 |
|
|
|a (DE-627)NLM351452311
|
| 035 |
|
|
|a (NLM)36634272
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Wang, Xiaoyan
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Colloid Electrolyte with Changed Li+ Solvation Structure for High-Power, Low-Temperature Lithium-Ion Batteries
|
| 264 |
|
1 |
|c 2023
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 23.03.2023
|
| 500 |
|
|
|a Date Revised 23.03.2023
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2023 Wiley-VCH GmbH.
|
| 520 |
|
|
|a Lithium-ion batteries currently suffer from low capacity and fast degradation under fast charging and/or low temperatures. In this work, a colloid liquid electrolyte (CLE) is designed, where the trace amount of lithium thiocarbonate (LTC) colloids in commercial carbonate electrolyte (1 m LiPF6 in ethylene carbonate/dimethyl carbonate) not only boosts up σLi+ but also improves the Li+ transfer kinetics at LiNi0.8 Co0.15 Al0.05 O2 (NCA) cathode/electrolyte interface. The competitive coordination of LTCs with anions and solvents facilitates the dissociation of lithium salts and Li+ decoupling, dramatically enhancing the σLi+ (15 to 4.5 mS cm-1 at 30 and -20 °C, respectively); meanwhile, the desolvation process is accelerated. It demonstrates that LTC colloids induce an ≈5 nm ultrathin Li2 CO3 -rich cathode electrolyte interface and infuse the grain boundary of NCA particles, enhancing interfacial Li+ transfer and inhibiting the particle cracks during cycling. Consequently, the Li||CLE||NCA battery delivers a maximum capacity of 135 mAh g-1 at a 10 C rate with 80% retention after 2000 cycles. Moreover, the fast-charging capability under a sub-zero environment is proved (122 mAh g-1 with 90% retention after 400 cycles at 2 C and -10 °C). This strategy for tailoring the interfacial charge transfer appears generalizable and can practically be extended to next-generation energy-storage systems
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a cathode electrolyte interface
|
| 650 |
|
4 |
|a coordination environment
|
| 650 |
|
4 |
|a electrolytes
|
| 650 |
|
4 |
|a fast charging
|
| 650 |
|
4 |
|a lithium-ion batteries
|
| 700 |
1 |
|
|a Yang, Le
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Ahmad, Niaz
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Ran, Leguan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Shao, Ruiwen
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yang, Wen
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 35(2023), 12 vom: 26. März, Seite e2209140
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:35
|g year:2023
|g number:12
|g day:26
|g month:03
|g pages:e2209140
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202209140
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 35
|j 2023
|e 12
|b 26
|c 03
|h e2209140
|