Temperature Dependence of Clumped Isotopes (∆47) in Aragonite
© 2022 The Authors.
| Veröffentlicht in: | Geophysical research letters. - 1984. - 49(2022), 20 vom: 28. Okt., Seite e2022GL099479 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2022
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| Zugriff auf das übergeordnete Werk: | Geophysical research letters |
| Schlagworte: | Journal Article aragonite clumped isotopes mollusk paleoclimate temperature |
| Zusammenfassung: | © 2022 The Authors. Clumped isotope thermometry can independently constrain the formation temperatures of carbonates, but a lack of precisely temperature-controlled calibration samples limits its application on aragonites. To address this issue, we present clumped isotope compositions of aragonitic bivalve shells grown under highly controlled temperatures (1-18°C), which we combine with clumped isotope data from natural and synthetic aragonites from a wide range of temperatures (1-850°C). We observe no discernible offset in clumped isotope values between aragonitic foraminifera, mollusks, and abiogenic aragonites or between aragonites and calcites, eliminating the need for a mineral-specific calibration or acid fractionation factor. However, due to non-linear behavior of the clumped isotope thermometer, including high-temperature (>100°C) datapoints in linear clumped isotope calibrations causes them to underestimate temperatures of cold (1-18°C) carbonates by 2.7 ± 2.0°C (95% confidence level). Therefore, clumped isotope-based paleoclimate reconstructions should be calibrated using samples with well constrained formation temperatures close to those of the samples |
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| Beschreibung: | Date Revised 09.09.2024 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 0094-8276 |
| DOI: | 10.1029/2022GL099479 |