Controlled Iodine Phase Transfer of Covalent Organic Framework Membranes for Instant but Sustained Disinfection
Freestanding membranes of CuCl2-implanted TpPa covalent organic frameworks (COFs) were mechanochemically produced. The resulting membrane had a high I2 adsorption capacity (566.78 g·mol-1) in cyclohexane, which corresponds to 2.2I2 per unit cell with 1.3I2 immobilized on 3Cl- ions (60%) and 0.9 on 3...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 39(2023), 1 vom: 10. Jan., Seite 597-609 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2023
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article Research Support, Non-U.S. Gov't Metal-Organic Frameworks Iodine 9679TC07X4 |
| Zusammenfassung: | Freestanding membranes of CuCl2-implanted TpPa covalent organic frameworks (COFs) were mechanochemically produced. The resulting membrane had a high I2 adsorption capacity (566.78 g·mol-1) in cyclohexane, which corresponds to 2.2I2 per unit cell with 1.3I2 immobilized on 3Cl- ions (60%) and 0.9 on 3N atoms (40%). Upon being placed in aqueous media, the membrane released 61.1% of its loaded I2 mainly by its Cl- ions within 10 min and the remaining 38.9% mainly from its N atoms within about 5 h. Thanks to that, the COF membranes loaded with 1.5 mg of I2 could be repetitively utilized to kill about 108 CFU/mL E. coli in 0.5-3 min at least five times, after which the membranes could retain their bactericidal activity for 4 h against 108 CFU/mL E. coli. This highlights the promising application of I2-loaded TpPa-CuCl2 COF membranes for instant and sustained disinfection |
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| Beschreibung: | Date Completed 11.01.2023 Date Revised 01.02.2023 published: Print-Electronic Citation Status MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/acs.langmuir.2c02892 |