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231226s2023 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202205578
|2 doi
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|a pubmed24n1169.xml
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|a eng
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|a Du, Guanxin
|e verfasserin
|4 aut
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|a Hybridization Engineering of Oxyfluoride Aluminosilicate Glass for Construction of Dual-Phase Optical Ceramics
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|c 2023
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|a Text
|b txt
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 20.03.2023
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|a Date Revised 20.03.2023
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2023 Wiley-VCH GmbH.
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|a The construction of transparent ceramics under mild conditionsand standard atmospheric pressure has great scientific and technological potential; however, it remains difficult to achieve when conventional ceramic sintering techniques are used. Herein, a mild strategy for constructing dual-phase optical ceramics with high crystallinity (>90%) based on the stepped dual-phase crystallization of hybridized aluminosilicate glass is presented. Theoretical and experimental studies reveal that the hybridization of the glass system enables a new balance between the glass-forming ability and crystallization and can overcome the uncontrolled devitrification phenomenon during the dense crystallization of glass. Transparent hybridized oxide-fluoride ceramics with fiber geometry and dual-phase microstructures are also successfully fabricated. The generality of the strategy is confirmed, and transparent ceramics with various chemical compositions and phase combinations are prepared. Additionally, the cross-section of the ceramic fibers can be easily tuned into a circle, square, trapezoid, or even a triangle. Furthermore, the practical applications of optical ceramics for lighting and X-ray imaging are demonstrated. The findings described here suggest a major step toward expanding the scope of optical ceramics
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|a Journal Article
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|a ceramics
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|a crystallization
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|a glass
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|a glass-ceramics
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|a luminescence
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|a Wen, Shaofei
|e verfasserin
|4 aut
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|a Zhao, Junjie
|e verfasserin
|4 aut
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|a Ran, Peng
|e verfasserin
|4 aut
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|a Wang, Dazhao
|e verfasserin
|4 aut
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|a Wei, Lei
|e verfasserin
|4 aut
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|a Qiao, Xvsheng
|e verfasserin
|4 aut
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|a Yang, Yang
|e verfasserin
|4 aut
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|a Qiu, Jianrong
|e verfasserin
|4 aut
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| 700 |
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|a Zhou, Shifeng
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 35(2023), 11 vom: 09. März, Seite e2205578
|w (DE-627)NLM098206397
|x 1521-4095
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|g volume:35
|g year:2023
|g number:11
|g day:09
|g month:03
|g pages:e2205578
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|u http://dx.doi.org/10.1002/adma.202205578
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