Pressure cells for in situ neutron total scattering : time and real-space resolution during deuterium absorption
© Kazutaka Ikeda et al. 2022.
| Veröffentlicht in: | Journal of applied crystallography. - 1998. - 55(2022), Pt 6 vom: 01. Dez., Seite 1631-1639 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2022
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| Zugriff auf das übergeordnete Werk: | Journal of applied crystallography |
| Schlagworte: | Journal Article hydrogen storage in situ neutron total scattering pair distribution functions reverse Monte Carlo methods |
| Zusammenfassung: | © Kazutaka Ikeda et al. 2022. In situ gas-loading sample holders for two-dimensionally arranged detectors in time-of-flight neutron total scattering experiments have been developed to investigate atomic arrangements during deuterium absorption using time and real-space resolution. A single-crystal sapphire container was developed that allows conditions of 473 K and 10 MPa hydrogen gas pressure. High-resolution transient measurements detected deuterium absorption by palladium that proceeded within a few seconds. A double-layered container with thick- and thin-walled vanadium allowed conditions of 423 K and 10 MPa hydrogen gas pressure. The deuterium occupation sites of a lanthanum-nickel-aluminium alloy are discussed in detail on the basis of real-space high-resolution data obtained from in situ neutron scattering measurements and reverse Monte Carlo structural modeling |
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| Beschreibung: | Date Revised 27.12.2022 published: Electronic-eCollection Citation Status PubMed-not-MEDLINE |
| ISSN: | 0021-8898 |
| DOI: | 10.1107/S1600576722010561 |