3D Cold-Trap Environment Printing for Long-Cycle Aqueous Zn-Ion Batteries

© 2022 Wiley-VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 35(2023), 9 vom: 20. März, Seite e2209886
1. Verfasser: Lu, Hongyu (VerfasserIn)
Weitere Verfasser: Hu, Jisong, Zhang, Yan, Zhang, Kaiqi, Yan, Xiaoying, Li, Heqi, Li, Jianzhu, Li, Yujie, Zhao, Jingxin, Xu, Bingang
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2023
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article 3D cold-trap environment printing 3DCEP-MXene/Zn-P anodes Zn-ion batteries lattice matching physical confinement effects
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520 |a Zn powder (Zn-P)-based anodes are always regarded as ideal anode candidates for zinc ion batteries owing to their low cost and ease of processing. However, the intrinsic negative properties of Zn-P-based anodes such as easy corrosion and uncontrolled dendrite growth have limited their further applications. Herein, a novel 3D cold-trap environment printing (3DCEP) technology is proposed to achieve the MXene and Zn-P (3DCEP-MXene/Zn-P) anode with highly ordered arrangement. Benefitting from the unique inhibition mechanism of high lattice matching and physical confinement effects within the 3DCEP-MXene/Zn-P anode, it can effectively homogenize the Zn2+ flux and alleviate the Zn deposition rate of the 3DCEP-MXene/Zn-P anode during Zn plating-stripping. Consequently, the 3DCEP-MXene/Zn-P anode exhibits a superior cycling lifespan of 1400 h with high coulombic efficiency of ≈9.2% in symmetric batteries. More encouragingly, paired with MXene and Co doped MnHCF cathode via 3D cold-trap environment printing (3 DCEP-MXene/Co-MnHCF), the 3DCEP-MXene/Zn-P//3DCEP-MXene/Co-MnHCF full battery delivers high cyclic durability with the capacity retention of 95.7% after 1600 cycles. This study brings an inspired universal pathway to rapidly fabricate a reversible Zn anode with highly ordered arrangement in a cold environment for micro-zinc storage systems 
650 4 |a Journal Article 
650 4 |a 3D cold-trap environment printing 
650 4 |a 3DCEP-MXene/Zn-P anodes 
650 4 |a Zn-ion batteries 
650 4 |a lattice matching 
650 4 |a physical confinement effects 
700 1 |a Hu, Jisong  |e verfasserin  |4 aut 
700 1 |a Zhang, Yan  |e verfasserin  |4 aut 
700 1 |a Zhang, Kaiqi  |e verfasserin  |4 aut 
700 1 |a Yan, Xiaoying  |e verfasserin  |4 aut 
700 1 |a Li, Heqi  |e verfasserin  |4 aut 
700 1 |a Li, Jianzhu  |e verfasserin  |4 aut 
700 1 |a Li, Yujie  |e verfasserin  |4 aut 
700 1 |a Zhao, Jingxin  |e verfasserin  |4 aut 
700 1 |a Xu, Bingang  |e verfasserin  |4 aut 
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773 1 8 |g volume:35  |g year:2023  |g number:9  |g day:20  |g month:03  |g pages:e2209886 
856 4 0 |u http://dx.doi.org/10.1002/adma.202209886  |3 Volltext 
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