Construction of Metal-Organic Framework Films via Crosslinking-Induced Assembly

© 2022 Wiley-VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 35(2023), 9 vom: 23. März, Seite e2209777
1. Verfasser: Li, Hongfeng (VerfasserIn)
Weitere Verfasser: Shi, Haohao, Chen, Xinyi, Ren, Zhen, Shen, Yu, Wu, Peng, Fan, Yun, Zhang, Xinglong, Shi, Wenxiong, Liao, Honggang, Zhang, Suoying, Zhang, Weina, Huo, Fengwei
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2023
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article crosslinking-induced assembly fluorescent films metal-organic frameworks modulators porous films
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520 |a The construction of metal-organic framework (MOF) films is a crucial step for integrating them into technical applications. However, due to the crystallization nature, it is difficult to grow most MOFs spontaneously or process them into films. Here, a convenient strategy is demonstrated for constructing MOF films by using modulators to achieve homogeneous assembly of MOF clusters. Small clusters in the early growth steps of MOFs can be stabilized by modulators to form fluidic precursors with good processibility. Then, simple removal of modulators will trigger the crosslinking of MOF clusters and lead to the formation of continuous films. This strategy is universal for the fabrication of several types of MOF films with large scale and controllable thickness, which can be deposited on a variety of substrates as well as can be patterned in micro/nano resolution. Additionally, versatile composite MOF films can be easily synthesized by introducing functional materials during the crosslinking process, which brings them broader application prospects 
650 4 |a Journal Article 
650 4 |a crosslinking-induced assembly 
650 4 |a fluorescent films 
650 4 |a metal-organic frameworks 
650 4 |a modulators 
650 4 |a porous films 
700 1 |a Shi, Haohao  |e verfasserin  |4 aut 
700 1 |a Chen, Xinyi  |e verfasserin  |4 aut 
700 1 |a Ren, Zhen  |e verfasserin  |4 aut 
700 1 |a Shen, Yu  |e verfasserin  |4 aut 
700 1 |a Wu, Peng  |e verfasserin  |4 aut 
700 1 |a Fan, Yun  |e verfasserin  |4 aut 
700 1 |a Zhang, Xinglong  |e verfasserin  |4 aut 
700 1 |a Shi, Wenxiong  |e verfasserin  |4 aut 
700 1 |a Liao, Honggang  |e verfasserin  |4 aut 
700 1 |a Zhang, Suoying  |e verfasserin  |4 aut 
700 1 |a Zhang, Weina  |e verfasserin  |4 aut 
700 1 |a Huo, Fengwei  |e verfasserin  |4 aut 
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773 1 8 |g volume:35  |g year:2023  |g number:9  |g day:23  |g month:03  |g pages:e2209777 
856 4 0 |u http://dx.doi.org/10.1002/adma.202209777  |3 Volltext 
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