N-Doped TiO2 Coupled with Manganese-Substituted Phosphomolybdic Acid Composites As Efficient Photocatalysis-Fenton Catalysts for the Degradation of Rhodamine B
The effectiveness of photocatalytic and Fenton reactions in the synergistic treatment of water pollution problems has become indisputable. In this paper, nitrogen-doped TiO2 was selected as the catalyst for the photocatalytic reaction and manganese-substituted phosphomolybdic acid was used as the Fe...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1999. - 38(2022), 50 vom: 20. Dez., Seite 15817-15826 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2022
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article Research Support, Non-U.S. Gov't titanium dioxide 15FIX9V2JP rhodamine B K7G5SCF8IL phosphomolybdic acid RN225F04V1 Manganese 42Z2K6ZL8P mehr... |
| Zusammenfassung: | The effectiveness of photocatalytic and Fenton reactions in the synergistic treatment of water pollution problems has become indisputable. In this paper, nitrogen-doped TiO2 was selected as the catalyst for the photocatalytic reaction and manganese-substituted phosphomolybdic acid was used as the Fenton reagent, the two of which were combined together by acid impregnation to construct a binary photocatalysis-Fenton composite catalyst. The degradation experiments of the composite catalyst on RhB indicated that under UV-vis irradiation, the composite catalyst could degrade RhB almost completely within 8 min, and the degradation rate was 19.7 times higher than that of N-TiO2, exhibiting a superior degradation ability. Simultaneously, a series of characterization methods were employed to analyze the structure, morphology, and optical properties of the catalysts. The results demonstrated that the nitrogen doping not only expanded the photo response range of TiO2 but reduced the work function of TiO2, which facilitated the transfer of electrons to the loaded Mn-HPMo side and further promoted the electron-hole separation efficiency. In addition, the introduction of Mn-HPMo provided three pathways for the activation of hydrogen peroxide, which enhanced the degradation activity. This study provides novel insights into the construction of binary and efficient catalysts with multiple hydroxyl radical generation pathways |
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| Beschreibung: | Date Completed 21.12.2022 Date Revised 06.01.2023 published: Print-Electronic Citation Status MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/acs.langmuir.2c02755 |