|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM349951527 |
| 003 |
DE-627 |
| 005 |
20231226043842.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231226s2023 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202209210
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1166.xml
|
| 035 |
|
|
|a (DE-627)NLM349951527
|
| 035 |
|
|
|a (NLM)36482825
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Yu, Jia
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Breaking the Electronic Conductivity Bottleneck of Manganese Oxide Family for High-Power Fluorinated Graphite Composite Cathode by Ligand-Field High-Dimensional Constraining Strategy
|
| 264 |
|
1 |
|c 2023
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 24.02.2023
|
| 500 |
|
|
|a Date Revised 24.02.2023
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2022 Wiley-VCH GmbH.
|
| 520 |
|
|
|a Primary lithium fluorinated graphite (Li/CFx ) batteries with superior energy density are an indispensable energy supply for multiple fields but suffer from sluggish reaction kinetics of the CFx cathode. Designing composite cathodes emerges as a solution to this problem. Despite the optimal composite component for CFx , the manganese oxide family represented by MnO2 is still faced with an intrinsic electronic conductivity bottleneck, which severely limits the power density of the composite cathode. Here, a cation-induced high-dimensional constraining strategy from the perspective of ligand-field stacking structure topological design, which breaks the molecular orbital hybridization of pristine semiconductive oxides to transform them into the high-conductivity metallic state while competitively maintaining structural stability, is proposed. Through first-principles phase diagram calculations, mixed-valent Mn5 O8 ( Mn 2 2 + Mn 3 4 + O 8 ${\rm{Mn}}_2^{2 + }{\rm{Mn}}_3^{4 + }{{\rm{O}}_8}$ ) is explored as an ideal high-dimensional constraining material with satisfied conductivity and large-scale production feasibility. Experiments demonstrate that the as-proposed CFx Mn5 O8 composite cathode achieves 2.36 times the power density (11399 W kg-1 ) of pristine CFx and a higher CFx conversion ratio (86%). Such a high-dimensional field-constraining strategy is rooted in the established four-quadrant electronic structure tuning framework, which fundamentally changes the orbital symmetry under the ligand field to overcome the common conductivity challenge of wide transition metal oxide materials
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a electronic conductivities
|
| 650 |
|
4 |
|a fluorinated graphite
|
| 650 |
|
4 |
|a high-dimensional constraining
|
| 650 |
|
4 |
|a ligand-field stacking topology
|
| 650 |
|
4 |
|a transition metal oxides
|
| 700 |
1 |
|
|a Wang, Da
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wang, Guoxin
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Cui, Yanhua
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Shi, Siqi
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 35(2023), 8 vom: 09. Feb., Seite e2209210
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:35
|g year:2023
|g number:8
|g day:09
|g month:02
|g pages:e2209210
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202209210
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 35
|j 2023
|e 8
|b 09
|c 02
|h e2209210
|