Electron-Phonon Coupling Suppression by Enhanced Lattice Rigidity in 2D Perovskite Single Crystals for High-Performance X-Ray Detection
© 2022 Wiley-VCH GmbH.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 35(2023), 7 vom: 15. Feb., Seite e2208875 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2023
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| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article 2D perovskite X-ray detection electron-phonon coupling high sensitivity lattice rigidity |
| Zusammenfassung: | © 2022 Wiley-VCH GmbH. 2D Dion-Jacobson (DJ) perovskite single crystals (PSCs) usually demonstrate better X-ray detection performance than Ruddlesden-Popper (RP) PSCs. However, the mechanism of the improved performance is still elusive. Here, by the aid of strong interactions between dimethylbiguanide (DGA) and PbI2 , a novel DJ-perovskitoid (DGA)PbI4 is designed. From the comparison of (DGA)PbI4 to other 2D PSCs, it is discovered that the tiniest lattice distortion and increased hydrogen bonds in the atom-scaled analysis strengthen lattice rigidity and weaken electron-phonon coupling to suppress disordered scattering of carriers, resulting in significantly improved carrier transport and stability. Therefore, high carrier mobility (78.1 cm2 V-1 s-1 ) and a pronounced sensitivity of 4869.0 µC Gyair -1 cm-2 are achieved using (DGA)PbI4 , which are the best in 2D Pb-based PSC devices to date. Finally, the (DGA)PbI4 devices exhibit good spatial resolution in X-ray imaging and excellent long-term stability to work as a promising candidate for medical diagnostics and nondestructive determination |
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| Beschreibung: | Date Completed 23.02.2023 Date Revised 23.02.2023 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.202208875 |