Super-Assembled Multi-Level Asymmetric Mesochannels for Coupled Accelerated Dual-Ion Selective Transport
© 2022 Wiley-VCH GmbH.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 35(2023), 7 vom: 01. Feb., Seite e2208903 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2023
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| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article dual-ion selectivity mesochannels multi-level asymmetry super-assembly |
| Zusammenfassung: | © 2022 Wiley-VCH GmbH. Asymmetric nanofluidic devices hold great potential in energy conversion applications. However, most of the existing asymmetric nanofluidic devices remain a single-level asymmetric structure and a single-ion selective layer, which results in weak ion selectivity and limited energy conversion efficiency. Herein, a multi-level asymmetric mesoporous carbon/anodized aluminum/mesoporous silica (MC/AAO/MS) nanofluidic device with abundant and ordered mesochannels is constructed from super-assembly strategy. The resultant MC/AAO/MS exhibits diode-like ion transport and outstanding ion storage-release performance. Importantly, MC/AAO/MS couples the MC and MS dual-ion selective layers, which ensures a high ionic conductance and evidently enhances the cation selectivity. Thereby, the MC/AAO/MS demonstrates ascendant salinity gradient energy conversion performance. The power density and conversion efficiency can reach up to 5.37 W m-2 and 32.79%, respectively. Noteworthy, a good energy conversion performance of 63 mW m-2 can still be achieved upon high working area, outperforming 300% of the performance of MC/AAO and MS/AAO single-level asymmetric nanochannels. Theoretical calculation further verifies that the multi-level asymmetric structure and dual-ion selective transport are the reason for the enhanced cation selectivity and energy conversion efficiency. This work opens a new avenue for constructing multi-level asymmetric structured nanofluidic devices for various applications |
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| Beschreibung: | Date Completed 23.02.2023 Date Revised 23.02.2023 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.202208903 |