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231226s2023 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202203420
|2 doi
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|a pubmed24n1163.xml
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|a (DE-627)NLM349118108
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|a (NLM)36398539
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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| 100 |
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|a Liu, Depei
|e verfasserin
|4 aut
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| 245 |
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|a A Template Editing Strategy to Create Interlayer-Confined Active Species for Efficient and Durable Oxygen Evolution Reaction
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|c 2023
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Completed 13.01.2023
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|a Date Revised 13.01.2023
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2022 Wiley-VCH GmbH.
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|a Substantial overpotentials and insufficient and unstable active sites of oxygen evolution reaction (OER) electrocatalysts limit their efficiency and stability in OER-related energy conversion and storage technologies. Here, a template editing strategy is proposed to graft highly active catalytic species onto highly conductive rigid frameworks to tackle this challenge. As a successful attempt, two types of NiO6 units of layered Ni BDC (BDC stands for 1,4-benzenedicarboxylic acid) metal organic frameworks are selectively edited by chemical etching-assisted electroxidation to create layered γ-NiOOH with intercalated Ni-O species. In such an interlayer-confined intercalated architecture, the large interlayer space with high ion permeability offers an ideal reaction region to sufficiently expose the OER active sites comprising high-density intercalated Ni-O species, which also suppresses the undesirable γ to β phase transformation, thus exhibiting efficient and durable OER activity. As a result, water oxidation can occur at an extremely low overpotential of 130 mV and affords 1000 h stability at 100 mA cm-2 . The strategy conceptually shows the possibility of achieving stable homogeneous-like catalysis in heterogeneous catalysis
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|a Journal Article
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|a Ni hydroxides
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|a interlayer-confined active species
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|a oxygen evolution reaction
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|a template editing strategy
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| 700 |
1 |
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|a Yan, Yuandong
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Li, Hu
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Liu, Duanduan
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Yang, Yandong
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Li, Taozhu
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Du, Yu
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Yan, Shicheng
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Yu, Tao
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zhou, Wei
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Cui, Peixin
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zou, Zhigang
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 35(2023), 2 vom: 07. Jan., Seite e2203420
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
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|g volume:35
|g year:2023
|g number:2
|g day:07
|g month:01
|g pages:e2203420
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|u http://dx.doi.org/10.1002/adma.202203420
|3 Volltext
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