Fresnel Diffraction Strategy Enables the Fabrication of Flexible Superomniphobic Surfaces

Doubly re-entrant surfaces inspired by springtails exhibit excellent repellency to low-surface-tension liquid. However, the flexible doubly re-entrant surfaces are difficult to fabricate, especially for the overhang of the structure. Herein, we demonstrate a simple Fresnel aperture diffraction modul...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 38(2022), 47 vom: 29. Nov., Seite 14508-14516
1. Verfasser: Zhang, Zhonggang (VerfasserIn)
Weitere Verfasser: Pei, Guangyao, Zhao, Keli, Pang, Peng, Gao, Wei, Ye, Tao, Ma, Binghe, Luo, Jian, Deng, Jinjun
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2022
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Doubly re-entrant surfaces inspired by springtails exhibit excellent repellency to low-surface-tension liquid. However, the flexible doubly re-entrant surfaces are difficult to fabricate, especially for the overhang of the structure. Herein, we demonstrate a simple Fresnel aperture diffraction modulation strategy in microscale lithography coupled with a molding process to obtain the flexible doubly re-entrant superomniphobic surfaces with nanoscale overhangs. The negative nanoscale overhang features were formed in a single-layer photoresist due to the fine-modulation of the optical intensity fluctuation of the Fresnel aperture diffraction. The as-prepared flexible non-fluorinated polydimethylsiloxane (PDMS) doubly re-entrant microstructure based on the Fresnel aperture diffraction (D-BF) surface (without any additional treatments) could repel ethanol droplets (21.8 mN m-1) in the Cassie-Baxter state. The robust nanoscale overhangs obtained by the molding process enable the maximum breakthrough pressure for the low-surface-tension ethanol droplets on the D-BF surfaces up to about 230 Pa, allowing ethanol liquids with Weber numbers up to 8.7 to fully bounce off. The fabricated non-fluorinated D-BF superomniphobic surface maintains outstanding liquid repellency after the surface wettability modification and deformation test 
650 4 |a Journal Article 
700 1 |a Pei, Guangyao  |e verfasserin  |4 aut 
700 1 |a Zhao, Keli  |e verfasserin  |4 aut 
700 1 |a Pang, Peng  |e verfasserin  |4 aut 
700 1 |a Gao, Wei  |e verfasserin  |4 aut 
700 1 |a Ye, Tao  |e verfasserin  |4 aut 
700 1 |a Ma, Binghe  |e verfasserin  |4 aut 
700 1 |a Luo, Jian  |e verfasserin  |4 aut 
700 1 |a Deng, Jinjun  |e verfasserin  |4 aut 
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