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231226s2023 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202209402
|2 doi
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|a pubmed24n1161.xml
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|a (DE-627)NLM348553587
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|a eng
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|a Su, Yun
|e verfasserin
|4 aut
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|a High-Entropy Microdomain Interlocking Polymer Electrolytes for Advanced All-Solid-State Battery Chemistries
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|c 2023
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 05.01.2023
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|a Date Revised 11.01.2023
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2022 Wiley-VCH GmbH.
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|a All-solid-state polymer electrolytes (ASPEs) with excellent processivity are considered one of the most forward-looking materials for large-scale industrialization. However, the contradiction between improving the mechanical strength and accelerating the ionic migration of ASPEs has always been difficult to reconcile. Herein, a rational concept is raised of high-entropy microdomain interlocking ASPEs (HEMI-ASPEs), inspired by entropic elasticity well-known in polymer and biochemical sciences, by introducing newly designed multifunctional ABC miktoarm star terpolymers into polyethylene oxide for the first time. The tailor-made HEMI-ASPEs possess multifunctional polymer chains, which induce themselves to assemble into micro- and nanoscale dynamic interlocking networks with high topological structure entropy. HEMI-ASPEs achieve excellent toughness, considerable ionic conductivity, an appreciable lithium transference number (0.63), and desirable thermal stability (Td > 400 °C) for all-solid-state lithium metal batteries. The Li|HEMI-ASPE-Li|Li symmetrical cell shows a stable Li plating/stripping performance over 4000 h, and a LiFePO4 |HEMI-ASPE-Li|Li full cell exhibits a high capacity retention (≈96%) after 300 cycles. This work contributes an innovative design concept introducing high-entropy supramolecular dynamic networks for ASPEs
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|a Journal Article
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|a all-solid-state batteries
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|a high-entropy
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|a polymer electrolytes
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|a self-assembly
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|a Rong, Xiaohui
|e verfasserin
|4 aut
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|a Li, Hong
|e verfasserin
|4 aut
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|a Huang, Xuejie
|e verfasserin
|4 aut
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|a Chen, Liquan
|e verfasserin
|4 aut
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|a Liu, Binyuan
|e verfasserin
|4 aut
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|a Hu, Yong-Sheng
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 35(2023), 1 vom: 18. Jan., Seite e2209402
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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|g volume:35
|g year:2023
|g number:1
|g day:18
|g month:01
|g pages:e2209402
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|u http://dx.doi.org/10.1002/adma.202209402
|3 Volltext
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