Degradation of COD in antibiotic wastewater by a combination process of electrochemistry, hydroxyl-functionalized ball-milled zero-valent iron/Fe3O4 and Oxone

In this study, the significant iron-based material, hydroxyl-functionalized ball-milled zero-valent iron/Fe3O4 (HFB-ZVI/Fe3O4) was employed for the experiments. The performance of the Electro + HFB-ZVI/Fe3O4 + Oxone system for the degradation of chemical oxygen demand (COD) in antibiotic wastewater...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Environmental technology. - 1993. - 45(2024), 7 vom: 01. März, Seite 1259-1270
1. Verfasser: Wang, Chun-Feng (VerfasserIn)
Weitere Verfasser: Li, Yue-Yi, Li, Ai-Hong, Yang, Nan, Wang, Xiao-Wen, Li, Yin-Ming, Zhang, Ye
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Journal Article COD degradation HFB-ZVI/Fe3O4 Oxone electrolysis radicals quenching Wastewater Iron E1UOL152H7 potassium peroxymonosulfuric acid mehr... HL6A2XXU5D Anti-Bacterial Agents Water Pollutants, Chemical Hydroxyl Radical 3352-57-6 Ferrosoferric Oxide XM0M87F357 Sulfuric Acids
LEADER 01000caa a22002652c 4500
001 NLM348161174
003 DE-627
005 20250304005758.0
007 cr uuu---uuuuu
008 231226s2024 xx |||||o 00| ||eng c
024 7 |a 10.1080/09593330.2022.2141661  |2 doi 
028 5 2 |a pubmed25n1160.xml 
035 |a (DE-627)NLM348161174 
035 |a (NLM)36301731 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Wang, Chun-Feng  |e verfasserin  |4 aut 
245 1 0 |a Degradation of COD in antibiotic wastewater by a combination process of electrochemistry, hydroxyl-functionalized ball-milled zero-valent iron/Fe3O4 and Oxone 
264 1 |c 2024 
336 |a Text  |b txt  |2 rdacontent 
337 |a ƒaComputermedien  |b c  |2 rdamedia 
338 |a ƒa Online-Ressource  |b cr  |2 rdacarrier 
500 |a Date Completed 29.02.2024 
500 |a Date Revised 29.02.2024 
500 |a published: Print-Electronic 
500 |a Citation Status MEDLINE 
520 |a In this study, the significant iron-based material, hydroxyl-functionalized ball-milled zero-valent iron/Fe3O4 (HFB-ZVI/Fe3O4) was employed for the experiments. The performance of the Electro + HFB-ZVI/Fe3O4 + Oxone system for the degradation of chemical oxygen demand (COD) in antibiotic wastewater was investigated. A direct current was applied between a graphite plate anode and two iron plate cathodes, and a series of operational parameters, such as applied electric current, the dosage of HFB-ZVI/Fe3O4 composite, the dosage of Oxone, and initial solution pH, were explored to evaluate the oxidation process. The application of electric current enhanced the gradual degradation of COD and the increase of current intensity accelerated COD degradation. The neutral condition was favourable for the rapid degradation of COD in a short reaction time by the Electro + HFB-ZVI/Fe3O4 + Oxone process and promoted the degradation efficiency of COD. An increase of electric current gradually decreased the reaction solution pH, the larger the electric current applied in the reaction process, the lower the final pH of the reaction solution. Under the optimal experimental conditions (1 g/L HFB-ZVI/Fe3O4 composite, 0.3 g/L Oxone, current intensity = 500 mA, initial solution pH = 7.85), Electro + HFB-ZVI/Fe3O4 + Oxone achieved 99% COD degradation in antibiotic wastewater. Radicals quenching experiments indicated the contribution to COD degradation by hydroxyl radicals (HO•), sulphate radicals (SO4•-) and other oxidants were 66.03%, 24.014% and 9.756%, respectively. The possible mechanism of COD degradation in the Electro + HFB-ZVI/Fe3O4 + Oxone system was also discussed in this study. The findings in this work provided useful information for the treatment of wastewater 
650 4 |a Journal Article 
650 4 |a COD degradation 
650 4 |a HFB-ZVI/Fe3O4 
650 4 |a Oxone 
650 4 |a electrolysis 
650 4 |a radicals quenching 
650 7 |a Wastewater  |2 NLM 
650 7 |a Iron  |2 NLM 
650 7 |a E1UOL152H7  |2 NLM 
650 7 |a potassium peroxymonosulfuric acid  |2 NLM 
650 7 |a HL6A2XXU5D  |2 NLM 
650 7 |a Anti-Bacterial Agents  |2 NLM 
650 7 |a Water Pollutants, Chemical  |2 NLM 
650 7 |a Hydroxyl Radical  |2 NLM 
650 7 |a 3352-57-6  |2 NLM 
650 7 |a Ferrosoferric Oxide  |2 NLM 
650 7 |a XM0M87F357  |2 NLM 
650 7 |a Sulfuric Acids  |2 NLM 
700 1 |a Li, Yue-Yi  |e verfasserin  |4 aut 
700 1 |a Li, Ai-Hong  |e verfasserin  |4 aut 
700 1 |a Yang, Nan  |e verfasserin  |4 aut 
700 1 |a Wang, Xiao-Wen  |e verfasserin  |4 aut 
700 1 |a Li, Yin-Ming  |e verfasserin  |4 aut 
700 1 |a Zhang, Ye  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Environmental technology  |d 1993  |g 45(2024), 7 vom: 01. März, Seite 1259-1270  |w (DE-627)NLM098202545  |x 1479-487X  |7 nnas 
773 1 8 |g volume:45  |g year:2024  |g number:7  |g day:01  |g month:03  |g pages:1259-1270 
856 4 0 |u http://dx.doi.org/10.1080/09593330.2022.2141661  |3 Volltext 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_350 
951 |a AR 
952 |d 45  |j 2024  |e 7  |b 01  |c 03  |h 1259-1270