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231226s2023 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202206980
|2 doi
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|a pubmed24n1159.xml
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|a DE-627
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|e rakwb
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|a eng
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|a Suh, Bong Lim
|e verfasserin
|4 aut
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|a Dimensional Control of Highly Anisotropic and Transparent Conductive Coordination Polymers for Solution-Processable Large-Scale 2D Sheets
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|c 2023
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 13.01.2023
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|a Date Revised 13.01.2023
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2022 The Authors. Advanced Materials published by Wiley-VCH GmbH.
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|a Controlling the dimensional aspect of conductive coordination polymers is currently a key scientific interest. Herein, solution-based dimension control strategies are proposed for copper chloride thiourea (CuCl-TU) coordination polymers that enable centimeter-scale, 2D nanosheet formation for use as transparent electrodes. Despite the wide bandgap of CuCl-TU polymers (4.33 eV), through polaron-mediated electron transfer, the electrical conductivity of the 2D sheet at room temperature is able to reach 4.45 S cm-1 without intentional doping. This leads to a highly anisotropic electronic conductivity of up to the order of ≈103 differences, depending on the material orientation. Furthermore, by substituting alternative thiourea candidates, it is demonstrated that it is possible to predesign CuCl-TU structures with the desired functionality, stability, and porosity through dimensional control. These findings provide a blueprint to design next-generation transparent conducting materials that can operate at room temperature, thereby expanding their applicability to different fields
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|a Journal Article
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|a 2D materials
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|a dimension control
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|a nanosheets
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|a polarons
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|a transparent electrodes
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1 |
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|a Kang, Goun
|e verfasserin
|4 aut
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|a Yoon, Sun Mi
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Cho, Sanghyun
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Moon, Myoung-Woon
|e verfasserin
|4 aut
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|a Sung, Yun-Mo
|e verfasserin
|4 aut
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|a Kim, Min-Seok
|e verfasserin
|4 aut
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|a Hur, Kahyun
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 35(2023), 2 vom: 10. Jan., Seite e2206980
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
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|g volume:35
|g year:2023
|g number:2
|g day:10
|g month:01
|g pages:e2206980
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|u http://dx.doi.org/10.1002/adma.202206980
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