Bond-length distributions in ionically bonded materials with decomposition by coordination environment

© Motonari Sawada et al. 2022.

Détails bibliographiques
Publié dans:Journal of applied crystallography. - 1998. - 55(2022), Pt 5 vom: 01. Okt., Seite 1359-1367
Auteur principal: Sawada, Motonari (Auteur)
Autres auteurs: Iwamoto, Ryoga, Kotani, Takao, Sakakibara, Hirofumi
Format: Article en ligne
Langue:English
Publié: 2022
Accès à la collection:Journal of applied crystallography
Sujets:Journal Article ChemEnv Crystallography Open Database bond-length distributions ionic radii statistics
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520 |a The distributions are analysed of the bond lengths between cations and anions in nitrides, oxides and fluorides for which structural data are available in the Crystallography Open Database (https://www.crystallography.net/cod/). The distributions are decomposed according to analysis of the coordination environments of the cations, which are offered in the tool ChemEnv [Waroquiers, George, Horton, Schenk, Persson, Rignanese, Gonze & Hautier (2020). Acta Cryst. B76, 683-695]. The distributions show how well the concept of ionic radius works. Chemical trends can be observed from the obtained distributions. For example, the bond-length distribution for Sc-O is similar to that for Zr-O. The distributions for Mo-O and V-O show noteworthy similarity. Resources for reproducing all of the results are available at https://github.com/tkotani/CEBond, with additional results for nitrides and fluorides 
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