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231226s2021 xx |||||o 00| ||eng c |
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|a 10.1021/acs.organomet.1c00100
|2 doi
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|a pubmed24n1155.xml
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|a (DE-627)NLM346748224
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|a (NLM)36158566
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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| 100 |
1 |
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|a Magallón, Carla
|e verfasserin
|4 aut
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| 245 |
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|a Well-Defined Aryl-FeII Complexes in Cross-Coupling and C-H Activation Processes
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|c 2021
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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| 338 |
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Revised 28.09.2022
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2021 American Chemical Society.
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|a Herein we explore the intrinsic organometallic reactivity of iron embedded in a tetradentate N3C macrocyclic ligand scaffold that allows the stabilization of aryl-Fe species, which are key intermediates in Fe-catalyzed cross-coupling and C-H functionalization processes. This study covers C-H activation reactions using Me L H and FeCl2, biaryl C-C coupling product formation through reaction with Grignard reagents, and cross-coupling reactions using Me L Br or H L Br in combination with Fe0(CO)5. Synthesis under light irradiation and moderate heating (50 °C) affords the aryl-FeII complexes [FeII(Br)( Me L)(CO)] (1 Me ) and [FeII( H L)(CO)2]Br (1 H ). Exhaustive spectroscopic characterization of these rare low-spin diamagnetic species, including their crystal structures, allowed the investigation of their intrinsic reactivity
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|a Journal Article
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1 |
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|a Planas, Oriol
|e verfasserin
|4 aut
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1 |
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|a Roldán-Gómez, Steven
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Luis, Josep M
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Company, Anna
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Ribas, Xavi
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Organometallics
|d 1998
|g 40(2021), 9 vom: 10. Mai, Seite 1195-1200
|w (DE-627)NLM098167103
|x 0276-7333
|7 nnns
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| 773 |
1 |
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|g volume:40
|g year:2021
|g number:9
|g day:10
|g month:05
|g pages:1195-1200
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|u http://dx.doi.org/10.1021/acs.organomet.1c00100
|3 Volltext
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|d 40
|j 2021
|e 9
|b 10
|c 05
|h 1195-1200
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