Textural Characterization by Using an Alternative Langmuir Isotherm and a New Thickness Function
Samples with micropores can not be adequately described by using the Langmuir isotherm. The Langmuir expression is obtained by using the monolayer assumption, which is not valid in samples with micropores. Then, we propose to include in the isotherm a corrective parameter related to the sample poros...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1999. - 38(2022), 39 vom: 04. Okt., Seite 11972-11982 |
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| Weitere Verfasser: | , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2022
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | Samples with micropores can not be adequately described by using the Langmuir isotherm. The Langmuir expression is obtained by using the monolayer assumption, which is not valid in samples with micropores. Then, we propose to include in the isotherm a corrective parameter related to the sample porosity. We show that the modified isotherm enables us to describe the experimental values for different samples (aluminas, clays, silicas, zeolites, and zirconias) in low and full relative pressure ranges. Indeed, a new thickness function for the adsorbate layer in terms of the relative pressure is proposed. Then, a better description of the external surface areas, mesopores, and micropores of the samples can be obtained with the new thickness function. The VBS model with this new thickness shows a better pore distribution description |
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| Beschreibung: | Date Revised 04.10.2022 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/acs.langmuir.2c01721 |