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231226s2022 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.2c01021
|2 doi
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|a pubmed24n1148.xml
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|a (DE-627)NLM344709388
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|a (NLM)35951599
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|a DE-627
|b ger
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|e rakwb
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|a eng
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| 100 |
1 |
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|a Sun, Changsheng
|e verfasserin
|4 aut
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|a Formation of n-Hexane-in-DMF Nonaqueous Pickering Emulsions
|b ABC Triblock Worms versus AB Diblock Worms
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|c 2022
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Revised 23.08.2022
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Nonaqueous Pickering emulsions exhibit promising applications in many industrial areas but have been relatively less studied in the past. In this study, n-hexane-in-DMF nonaqueous Pickering emulsions stabilized by core cross-linked copolymer worms with mixed shells are demonstrated for the first time. Core cross-linked copolymer worms with mixed shells were prepared by seeded reversible addition-fragmentation chain transfer (RAFT) quasi-solution polymerization. Specifically, polystyrene-poly(4-vinylpyridine) (PS-P4VP) diblock copolymer worms were first prepared via RAFT-mediated dispersion polymerization in toluene under the given conditions using PS as both the macro-CTA and the stabilizer block. After the chemical cross-linking of P4VP cores, PS-P4VP diblock copolymer worms were chain-extended with LMA in DMF/toluene (1:9, weight ratio) mixed solvents, producing core cross-linked PS-P4VP-PLMA worms with PS/PLMA mixed shells. The as-prepared core cross-linked PS-P4VP-PLMA worms with mixed PS/PLMA shells were further utilized as Pickering emulsifiers for the generation of nonaqueous n-hexane-in-DMF Pickering emulsions. The emulsifying performances of mixed-shell copolymer worms were compared with those of their spherical and linear analogues with entirely identical chemical compositions as well as PS-P4VP diblock copolymer worm precursors, respectively
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|a Journal Article
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1 |
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|a Zhou, Shujing
|e verfasserin
|4 aut
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1 |
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|a Li, Jinjing
|e verfasserin
|4 aut
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1 |
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|a Qi, Chenze
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Gao, Yong
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 38(2022), 33 vom: 23. Aug., Seite 10128-10138
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:38
|g year:2022
|g number:33
|g day:23
|g month:08
|g pages:10128-10138
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|u http://dx.doi.org/10.1021/acs.langmuir.2c01021
|3 Volltext
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|d 38
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