Streaming Potential with Ideally Polarizable Electron-Conducting Substrates

With nonconducting substrates, streaming potential in sufficiently broad (vs Debye screening length) capillaries is well known to be a linear function of applied pressure (and coordinate along the capillary). This study for the first time explores streaming potential with ideally polarizable electro...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 38(2022), 32 vom: 16. Aug., Seite 9974-9980
1. Verfasser: Yaroshchuk, Andriy (VerfasserIn)
Weitere Verfasser: Zholkovskiy, Emiliy
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2022
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a With nonconducting substrates, streaming potential in sufficiently broad (vs Debye screening length) capillaries is well known to be a linear function of applied pressure (and coordinate along the capillary). This study for the first time explores streaming potential with ideally polarizable electron-conducting substrates and shows it to be a nonlinear function of both coordinate and applied pressure. Experimental manifestations can be primarily expected for streaming potentials arising along thin porous electron-conducting films experiencing solvent evaporation from the film side surface. Model predictions are in good qualitative agreement with literature experimental data 
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