|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM344438783 |
| 003 |
DE-627 |
| 005 |
20231226022757.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231226s2022 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202205677
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1148.xml
|
| 035 |
|
|
|a (DE-627)NLM344438783
|
| 035 |
|
|
|a (NLM)35924314
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Luo, Chao
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Roll-To-Roll Fabrication of Zero-Volume-Expansion Lithium-Composite Anodes to Realize High-Energy-Density Flexible and Stable Lithium-Metal Batteries
|
| 264 |
|
1 |
|c 2022
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 27.09.2022
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2022 Wiley-VCH GmbH.
|
| 520 |
|
|
|a The lithium (Li)-metal anode offers a promising solution for high-energy-density lithium-metal batteries (LMBs). However, the significant volume expansion of the Li metal during charging results in poor cycling stability as a result of the dendritic deposition and broken solid electrolyte interphase. Herein, a facile one-step roll-to-roll fabrication of a zero-volume-expansion Li-metal-composite anode (zeroVE-Li) is proposed to realize high-energy-density LMBs with outstanding electrochemical and mechanical stability. The zeroVE-Li possesses a sandwich-like trilayer structure, which consists of an upper electron-insulating layer and a bottom lithiophilic layer that synergistically guides the Li deposition from the bottom up, and a middle porous layer that eliminates volume expansion. This sandwich structure eliminates dendrite formation, prevents volume change during cycling, and provides outstanding flexibility to the Li-metal anode even at a practical areal capacity over 3.0 mAh cm-2 . Pairing zeroVE-Li with a commercial NMC811 or LCO cathode, flexible LMBs that offer a record-breaking figure of merit (FOM, 45.6), large whole-cell energy density (375 Wh L-1 , based on the volume of the anode, separator, cathode, and package), high-capacity retention (> 99.8% per cycle), and remarkable mechanical robustness under practical conditions are demonstrated
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a composite electrodes
|
| 650 |
|
4 |
|a dendrite deposition
|
| 650 |
|
4 |
|a flexible batteries
|
| 650 |
|
4 |
|a lithium metal
|
| 650 |
|
4 |
|a volume expansion
|
| 700 |
1 |
|
|a Hu, Hong
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Tian
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wen, Shujing
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wang, Ruo
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a An, Yanan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Chi, Shang-Sen
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wang, Jun
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wang, Chaoyang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Chang, Jian
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zheng, Zijian
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Deng, Yonghong
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 34(2022), 38 vom: 03. Sept., Seite e2205677
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:34
|g year:2022
|g number:38
|g day:03
|g month:09
|g pages:e2205677
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202205677
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 34
|j 2022
|e 38
|b 03
|c 09
|h e2205677
|