Noncovalently Cross-Linked Polymeric Materials Reinforced by Well-Designed In Situ-Formed Nanofillers
Noncovalently cross-linked polymeric materials generally exhibit lower mechanical robustness than traditional polymeric materials. Therefore, it is important to improve the mechanical properties of noncovalently cross-linked polymeric materials using an efficient and generalized approach. In this Pe...
Publié dans: | Langmuir : the ACS journal of surfaces and colloids. - 1985. - 38(2022), 30 vom: 02. Aug., Seite 9050-9063 |
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Auteur principal: | |
Autres auteurs: | , , |
Format: | Article en ligne |
Langue: | English |
Publié: |
2022
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Accès à la collection: | Langmuir : the ACS journal of surfaces and colloids |
Sujets: | Journal Article Review |
Résumé: | Noncovalently cross-linked polymeric materials generally exhibit lower mechanical robustness than traditional polymeric materials. Therefore, it is important to improve the mechanical properties of noncovalently cross-linked polymeric materials using an efficient and generalized approach. In this Perspective, we systematically summarized the recent development of noncovalently cross-linked polymeric materials reinforced by in situ-formed nanofillers. The synergy of high-density noncovalent interactions and in situ-formed rigid nanofillers provided an effective means for the fabrication of noncovalently cross-linked plastics with high mechanical strength. The design of in situ-formed tough nanofillers, which could deform and dissociate, endowed the noncovalently cross-linked hydrogels and elastomers with high toughness, excellent stretchability, elasticity, damage resistance, and damage tolerance. Benefiting from the well-designed in situ-formed nanofillers, these noncovalently cross-linked polymeric materials with enhanced mechanical strength still exhibited satisfactory healing, recycling, and reprocessing properties. Outlooks were provided to envision the remaining challenges to the further development and practical application of noncovalently cross-linked polymeric materials reinforced with in situ-formed nanofillers |
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Description: | Date Revised 02.08.2022 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
ISSN: | 1520-5827 |
DOI: | 10.1021/acs.langmuir.2c01380 |