Efficient Synthesis of Fe/N-Doped Carbon Nanotube as Highly Active Catalysts for Oxygen Reduction Reaction in Alkaline Media
It is of significant implication to fabricate high-performance, durable and low-cost catalysts toward to oxygen reduction reaction (ORR) to drive commercial application of fuel cells. In our work, we synthesize the Fe/N-CNT catalyst via one-pot grinding combined with calcination using a mixture of c...
| Publié dans: | Langmuir : the ACS journal of surfaces and colloids. - 1985. - 38(2022), 30 vom: 02. Aug., Seite 9310-9320 |
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| Auteur principal: | |
| Autres auteurs: | , , , , , , , |
| Format: | Article en ligne |
| Langue: | English |
| Publié: |
2022
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| Accès à la collection: | Langmuir : the ACS journal of surfaces and colloids |
| Sujets: | Journal Article |
| Résumé: | It is of significant implication to fabricate high-performance, durable and low-cost catalysts toward to oxygen reduction reaction (ORR) to drive commercial application of fuel cells. In our work, we synthesize the Fe/N-CNT catalyst via one-pot grinding combined with calcination using a mixture of carbamide, CNTs and iron salts as precursors, the as-synthesized catalysts show the structure that Fe nanoparticles are encapsulated in the tube of intertwined CNTs with abundant active sites. The catalyst is synthesized at 800 °C (Fe/N-CNT-800-20) obtain high graphitization degree and high N doped content, especially the high content and proportion of Fe-N and pyridinic-N, exhibiting outstanding ORR activity. Moreover, too high calcination temperature (850 °C) and high Fe content (25%) lead to the agglomeration of Fe during the calcination, which blocked some catalytic sites, leading to poor ORR activity. This facile synergy route will provide new thoughts for the fabrication and optimization of catalysts |
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| Description: | Date Revised 02.08.2022 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/acs.langmuir.2c01130 |