Ultrafine Silver Nanoparticle Encapsulated Porous Molecular Traps for Discriminative Photoelectrochemical Detection of Mustard Gas Simulants by Synergistic Size-Exclusion and Site-Specific Recognition
© 2022 Wiley-VCH GmbH.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 34(2022), 35 vom: 21. Sept., Seite e2202287 |
|---|---|
| 1. Verfasser: | |
| Weitere Verfasser: | , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2022
|
| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article chemical warfare agents hydrogen-bonded organic frameworks in situ photoreduction nanoparticle encapsulation photoelectrochemical sensing size selectivity Chemical Warfare Agents Silver 3M4G523W1G mehr... |
| Zusammenfassung: | © 2022 Wiley-VCH GmbH. The rapid, discriminative, and portable detection of highly toxic chemical warfare agents is extremely important for response to public security emergencies but remains a challenge. One plausible solution involves the integration of porous molecular traps onto a photoelectrochemical (PEC) sensor. Here, a fast and facile protocol is developed to fabricate sub-1 nm AgNPs encapsulated hydrogen-bonded organic framework (HOF) nanocomposite materials through an in situ photoreduction and subsequent encapsulation process. Compared to traditional semiconductors and selected metal-organic frameworks (MOF) materials, these AgNPsHOFs show significantly enhanced photocurrent. Most importantly, the portable PEC device based on AgNPs@HOF-101 can selectively recognize 13 different mustard gas simulants, including 2-chloroethyl ethyl sulfide (CEES), based on synergistic size-exclusion and specific recognition. The extremely low detection limit for CEES (15.8 nmol L-1 ), reusability (at least 30 cycles), and long-term working stability (at least 30 d) of the portable PEC device warrant its use as a chemical warfare agents (CWAs) sensor in practical field settings. More broadly, this work indicates that integrating porous molecular traps onto PEC sensors offers a promising strategy to further develop portable devices for CWAs detection with both ultrahigh sensitivity and selectivity |
|---|---|
| Beschreibung: | Date Completed 08.09.2022 Date Revised 08.09.2022 published: Print-Electronic Citation Status MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.202202287 |