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231226s2022 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202203281
|2 doi
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|a pubmed24n1142.xml
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|a eng
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| 100 |
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|a Xu, Jieru
|e verfasserin
|4 aut
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|a Long-Life Lithium-Metal All-Solid-State Batteries and Stable Li Plating Enabled by In Situ Formation of Li3 PS4 in the SEI Layer
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|c 2022
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Revised 25.08.2022
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2022 Wiley-VCH GmbH.
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|a An ultrastable and kinetically favorable interface is constructed between sulfide-poly(ethylene oxide) (PEO) composite solid electrolytes (CSEs) and lithium metal, via in situ formation of a solid electrolyte interphase (SEI) layer containing Li3 PS4 . A specially designed sulfide, lithium polysulfidophosphate (LPS), can distribute uniformly in the PEO matrix via a simple stirring process because of its complete solubility in acetonitrile solvent, which is advantageous for creating a homogeneous SEI layer. The CSE/Li interface with high Li+ transportation capability is stabilized quickly through in situ formation of a Li3 PS4 /Li2 S/LiF layer via the reaction between LPS and lithium metal to inhibit lithium dendrite growth. A Li/Li symmetric cell with the LPS-integrated CSE exhibits constant and small CSE/Li resistance of 10 Ω cm2 during cycling, delivering stable cycling for 3475 h at a current density of 0.2 mA cm-2 and a high critical current density of 0.9 mA cm-2 at 60 °C. Impressive electrochemical performance is also demonstrated for LiFePO4 /CSE/Li all-solid-state batteries with capacity of 127.6 mAh g-1 after 1000 cycles at 1 C
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|a Journal Article
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|a all-solid-state batteries
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|a composite solid electrolytes
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|a lithium-metal anodes
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|a solid electrolyte interphase
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|a sulfides
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1 |
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|a Li, Jiuming
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Li, Yongxing
|e verfasserin
|4 aut
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| 700 |
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|a Yang, Ming
|e verfasserin
|4 aut
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| 700 |
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|a Chen, Liquan
|e verfasserin
|4 aut
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|a Li, Hong
|e verfasserin
|4 aut
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| 700 |
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|a Wu, Fan
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 34(2022), 34 vom: 22. Aug., Seite e2203281
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
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|g volume:34
|g year:2022
|g number:34
|g day:22
|g month:08
|g pages:e2203281
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|u http://dx.doi.org/10.1002/adma.202203281
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