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231226s2022 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202202751
|2 doi
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|a eng
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|a Karak, Suvendu
|e verfasserin
|4 aut
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|a Maneuvering Applications of Covalent Organic Frameworks via Framework-Morphology Modulation
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|c 2022
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|a Text
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 09.12.2022
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|a Date Revised 09.12.2022
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2022 Wiley-VCH GmbH.
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|a Translating the performance of covalent organic frameworks (COFs) from laboratory to macroscopic reality demands specific morphologies. Thus, the advancement in morphological modulation has recently gained some momentum. A clear understanding of nano- to macroscopic architecture is critical to determine, optimize, and improve performances of this atomically precise porous material. Along with their chemical compositions and molecular frameworks, the prospect of morphology in various applications should be discussed and highlighted. A thorough insight into morphology versus application will help produce better-engineered COFs for practical implications. 2D and 3D frameworks can be transformed into various solids such as nanospheres, thin films, membranes, monoliths, foams, etc., for numerous applications in adsorption, separation photocatalysis, the carbon dioxide reduction, supercapacitors, and fuel cells. However, the research on COF chemistry mainly focuses on correlating structure to property, structure to morphology, and structure to applications. Here, critical insights on various morphological evolution and associated applications are provided. In each case, the underlying role of morphology is unveiled. Toward the end, a correlation between morphology and application is provided for the future development of COFs
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|a Journal Article
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|a Review
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|a covalent organic frameworks
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|a molecular structure
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|a morphology
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|a morphology modulation
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|a morphology-application design space
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|a Dey, Kaushik
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|a Banerjee, Rahul
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|t Advanced materials (Deerfield Beach, Fla.)
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|g 34(2022), 49 vom: 02. Dez., Seite e2202751
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|u http://dx.doi.org/10.1002/adma.202202751
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