Thermal Shock Fabrication of Ion-Stabilized Perovskite and Solar Cells
© 2022 Wiley-VCH GmbH.
Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 34(2022), 32 vom: 26. Aug., Seite e2203166 |
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1. Verfasser: | |
Weitere Verfasser: | , , , , , , , |
Format: | Online-Aufsatz |
Sprache: | English |
Veröffentlicht: |
2022
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Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
Schlagworte: | Journal Article ion migration perovskite solar cells thermal-shocking |
Zusammenfassung: | © 2022 Wiley-VCH GmbH. A highly crystalline tempered-glass-like perovskite grain structure with compressed surface lattice realized by a thermal-shocking fabrication is shown. The strained perovskite grain structure is stabilized by Cl- -reinforcing surface lattice and shows enhanced bonding energy and ionic activation temperature, which contributes to hysteresis-free operation of perovskite solar cells (PSCs) at much higher temperature up to 363 K in thermal-shocking-processed MAPbClx I3- x (T-MPI). The PSCs can be fabricated by a high-speed fully air process without post-annealing based on the scalable bar-coating technique. Both high efficiency and stability are achieved in T-MPI PSC with a power conversion efficiency (PCE) up to 22.99% and long-term operational stability with T80 lifetime exceeding 4000 h |
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Beschreibung: | Date Revised 10.08.2022 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
ISSN: | 1521-4095 |
DOI: | 10.1002/adma.202203166 |