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231226s2022 xx |||||o 00| ||eng c |
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|a 10.1002/jcc.26892
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|a pubmed24n1140.xml
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|a DE-627
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|a eng
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|a Chan, Bun
|e verfasserin
|4 aut
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|a Assessment of DLPNO-CCSD(T)-F12 and its use for the formulation of the low-cost and reliable L-W1X composite method
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|c 2022
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|a Text
|b txt
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 28.06.2022
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|a Date Revised 07.09.2022
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a © 2022 Wiley Periodicals LLC.
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|a In the present study, we have investigated the performance of RIJCOSX DLPNO-CCSD(T)-F12 methods for a wide range of systems. Calculations with a high-accuracy option ["DefGrid3 RIJCOSX DLPNO-CCSD(T1 )-F12"] extrapolated to the complete-basis-set limit using the maug-cc-pV[D+d,T+d]Z basis sets provides fairly good agreements with the canonical CCSD(T)/CBS reference for a diverse set of thermochemical and kinetic properties [with mean absolute deviations (MADs) of ~1-2 kJ mol-1 except for atomization energies]. On the other hand, the low-cost "RIJCOSX DLPNO-CCSD(T)-F12D" option leads to substantial deviations for certain properties, notably atomization energies (MADs of up to tens of kJ mol-1 ). With the high-accuracy CBS approach, we have formulated the L-W1X method, which further includes a low-cost core-valence plus scalar-relativistic term. It shows generally good accuracy. For improved accuracies in specific cases, we advise replacing maug-cc-pV(n+d)Z with jun-cc-pV(n+d)Z for the calculation of electron affinities, and using well-constructed isodesmic-type reactions to obtain atomization energies. For medium-sized systems, DefGrid3 RIJCOSX DLPNO-CCSD(T1 )-F12 calculations are several times faster than the corresponding canonical computation; the use of the local approximations (RIJCOSX and DLPNO) leads to a better scaling than that for the canonical calculation (from ~6-7 down to ~2-4 for our test systems). Thus, the DefGrid3 RIJCOSX DLPNO-CCSD(T1 )-F12 method, and the L-W1X protocol that based on it, represent a useful means for obtaining accurate thermochemical quantities for larger systems
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a DLPNO-CCSD(T)-F12
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|a W1X composite protocol
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|a thermochemistry
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|a Karton, Amir
|e verfasserin
|4 aut
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|i Enthalten in
|t Journal of computational chemistry
|d 1984
|g 43(2022), 21 vom: 05. Aug., Seite 1394-1402
|w (DE-627)NLM098138448
|x 1096-987X
|7 nnns
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|g volume:43
|g year:2022
|g number:21
|g day:05
|g month:08
|g pages:1394-1402
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|u http://dx.doi.org/10.1002/jcc.26892
|3 Volltext
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