Stepwise flotation separation of WEEE plastics by polymeric aluminum chloride towards source control of microplastics

Copyright © 2022 Elsevier Ltd. All rights reserved.

Bibliographische Detailangaben
Veröffentlicht in:Waste management (New York, N.Y.). - 1999. - 149(2022) vom: 15. Juli, Seite 1-10
1. Verfasser: Wang, Zhiyi (VerfasserIn)
Weitere Verfasser: Jiang, Hongru, Zhang, Yingshuang, Bian, Kai, Wang, Hui, Wang, Chongqing
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2022
Zugriff auf das übergeordnete Werk:Waste management (New York, N.Y.)
Schlagworte:Journal Article Flotation separation Plastic recycling Polymeric aluminum chloride Stepwise separation WEEE Microplastics Plastics Polyethylene Terephthalates Polymers mehr... Polystyrenes Aluminum Chloride 3CYT62D3GA Acrylonitrile MP1U0D42PE
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520 |a The mismanagement of waste electrical and electronic equipment (WEEE) resulted in numerous discarded plastics in the natural environment, and these waste plastics might experience aging, breaking, and migration, which becomes a crucial microplastic source. Sustainable management of WEEE plastics presents a considerable opportunity for resource recovery and microplastic pollution prevention. Flotation separation is a significant process of mechanical recycling, while most flotation methods can only deal with binary plastic mixtures. In this work, an advanced, stepwise, and sustainable flotation method was advocated to separate multi-plastics by polymeric aluminum chloride (PAC) modification. The abundant hydrophilic groups and environmental friendliness of PAC prompted us to further investigate the wetting effect. PAC had varied hydrophilization effects on acrylonitrile butadiene styrene (ABS) and polystyrene (PS) surfaces, but polyethylene terephthalate (PET) retained hydrophobicity. Treatment conditions, including PAC dosage, temperature, time, and pH were optimized. 100% of PET could be purified after primary separation, and the purities of ABS and PS could reach 100% and 97.4% after secondary separation, respectively. The strength of the interaction was determined by the different surface potentials and functional groups. In PAC solution, long-chain molecules or ions might interact with plastic surfaces electrostatically, and Al3+ could bridge long-chain molecules and plastic surfaces, thereby strengthening the polymer hydrophilicity. We further improved the PAC treatment process, and the reuse of PAC reduced modifier usage to 84.4 g/ton waste plastics, which was cost-effective in industrial applications. A preliminary evaluation of the energy consumption and environmental impact indicated that PAC treatment was superior to other modification methods. This work is an initial attempt at the stepwise separation of waste plastic and shows promising prospects for recycling plastic waste 
650 4 |a Journal Article 
650 4 |a Flotation separation 
650 4 |a Plastic recycling 
650 4 |a Polymeric aluminum chloride 
650 4 |a Stepwise separation 
650 4 |a WEEE 
650 7 |a Microplastics  |2 NLM 
650 7 |a Plastics  |2 NLM 
650 7 |a Polyethylene Terephthalates  |2 NLM 
650 7 |a Polymers  |2 NLM 
650 7 |a Polystyrenes  |2 NLM 
650 7 |a Aluminum Chloride  |2 NLM 
650 7 |a 3CYT62D3GA  |2 NLM 
650 7 |a Acrylonitrile  |2 NLM 
650 7 |a MP1U0D42PE  |2 NLM 
700 1 |a Jiang, Hongru  |e verfasserin  |4 aut 
700 1 |a Zhang, Yingshuang  |e verfasserin  |4 aut 
700 1 |a Bian, Kai  |e verfasserin  |4 aut 
700 1 |a Wang, Hui  |e verfasserin  |4 aut 
700 1 |a Wang, Chongqing  |e verfasserin  |4 aut 
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773 1 8 |g volume:149  |g year:2022  |g day:15  |g month:07  |g pages:1-10 
856 4 0 |u http://dx.doi.org/10.1016/j.wasman.2022.05.029  |3 Volltext 
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