Preparation of Monodisperse Bio-Based Polymer Particles via Dispersion Polymerization

Monodisperse bio-based polymer particles were successfully prepared through the dispersion polymerization of tulip-derived α-methylene-γ-butyrolactone (MBL) in N,N-dimethylformamide/ethanol (7/3, w/w) at 65 °C with poly(vinylpyrrolidone) (PVP) as a colloidal stabilizer. The diameter of the polymer p...

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Détails bibliographiques
Publié dans:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 38(2022), 23 vom: 14. Juni, Seite 7341-7345
Auteur principal: Onita, Katsuhiro (Auteur)
Autres auteurs: Onishi, Miku, Omura, Taro, Wakiya, Takeshi, Suzuki, Toyoko, Minami, Hideto
Format: Article en ligne
Langue:English
Publié: 2022
Accès à la collection:Langmuir : the ACS journal of surfaces and colloids
Sujets:Journal Article Polymers Water 059QF0KO0R
Description
Résumé:Monodisperse bio-based polymer particles were successfully prepared through the dispersion polymerization of tulip-derived α-methylene-γ-butyrolactone (MBL) in N,N-dimethylformamide/ethanol (7/3, w/w) at 65 °C with poly(vinylpyrrolidone) (PVP) as a colloidal stabilizer. The diameter of the polymer particles was well controlled by changing the composition of the reaction medium or PVP concentration. Furthermore, 100% bio-based poly(MBL) (PMBL) particles were prepared via the dispersion polymerization of MBL in water using hydrolyzed PMBL as a colloidal stabilizer, which was synthesized by hydrolysis of PMBL
Description:Date Completed 15.06.2022
Date Revised 16.08.2022
published: Print-Electronic
Citation Status MEDLINE
ISSN:1520-5827
DOI:10.1021/acs.langmuir.2c00946