|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM341163651 |
| 003 |
DE-627 |
| 005 |
20231226011138.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231226s2022 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202201779
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1137.xml
|
| 035 |
|
|
|a (DE-627)NLM341163651
|
| 035 |
|
|
|a (NLM)35593656
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Chen, Tingting
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a In Situ Synthesis of MOF-74 Family for High Areal Energy Density of Aqueous Nickel-Zinc Batteries
|
| 264 |
|
1 |
|c 2022
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 27.07.2022
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2022 Wiley-VCH GmbH.
|
| 520 |
|
|
|a Limited by single metal active sites and low electrical conductivity, designing nickel-based metal-organic framework (MOF) materials with high capacity and high energy density remains a challenge. Herein, a series of bi/multimetallic MOF-74 family materials in situ grown on carbon cloth (CC) by doping Mx+ ions in Ni-MOF-74 is fabricated: NiM-MOFCC (M = Mn2+ , Co2+ , Cu2+ , Zn2+ , Al3+ , Fe3+ ), and NiCoM-MOF@CC (M = Mn2+ , Zn2+ , Al3+ , Fe3+ ). The type and ratio of doping metal ions can be adjusted while the original topology is preserved. Different metal ions are confirmed by X-ray absorption fine structure (XAFS). Furthermore, these Ni-based MOF electrodes are directly utilized as cathodes for aqueous nickel-zinc batteries (NZBs). Among all the as-prepared electrodes, NiCo-MOF@CC-3 (NCM@CC-3), with an optimized Co/Ni ratio of 1:1, exhibits the best electrical conductivity, which is according to the density functional theory (DFT) theoretical calculations. The NCM@CC-3//Zn@CC battery achieves a high specific capacity of 1.77 mAh cm-2 , a high areal energy density of 2.97 mWh cm-2 , and high cycling stability of 83% capacity retention rate after 6000 cycles. The synthetic strategy based on the coordination effect of metal ions and the concept of binder-free electrodes provide a new direction for the synthesis of high-performance materials in the energy-storage field
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a MOF-74
|
| 650 |
|
4 |
|a areal energy density
|
| 650 |
|
4 |
|a conductivity
|
| 650 |
|
4 |
|a energy storage
|
| 650 |
|
4 |
|a metal-organic frameworks
|
| 650 |
|
4 |
|a nickel-zinc batteries
|
| 700 |
1 |
|
|a Wang, Fanfan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Cao, Shuai
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Bai, Yang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zheng, Shasha
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Li, Wenting
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Songtao
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Hu, Shu-Xian
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Pang, Huan
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 34(2022), 30 vom: 22. Juli, Seite e2201779
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:34
|g year:2022
|g number:30
|g day:22
|g month:07
|g pages:e2201779
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202201779
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 34
|j 2022
|e 30
|b 22
|c 07
|h e2201779
|