Highly Potassiophilic Graphdiyne Skeletons Decorated with Cu Quantum Dots Enable Dendrite-Free Potassium-Metal Anodes
© 2022 Wiley-VCH GmbH.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 34(2022), 29 vom: 01. Juli, Seite e2202685 |
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| Weitere Verfasser: | , , , , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2022
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| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article Al current collectors dendrite-free batteries graphdiyne potassiophilic materials potassium-metal batteries |
| Zusammenfassung: | © 2022 Wiley-VCH GmbH. Employing an Al foil current collector at the potassium anode side is an ideal choice to entail low-cost and high-energy potassium-metal batteries (PMBs). Nevertheless, the poor affinity between the potassium and the planar Al can cause uneven K plating/stripping and, hence, an undermined anode performance, which remains a significant challenge to be addressed. Herein, a nitrogen-doped carbongraphdiyne (NC@GDY)-modified Al current collector affording potassiophilic properties is proposed, which simultaneously suppresses the dendrite growth and prolongs the lifespan of K anodes. The thin and light modification layer (7 µm thick, with a mass loading of 500 µg cm-2 ) is fabricated by directly growing GDY nanosheets interspersed with Cu quantum dots on NC polyhedron templates. As a result, symmetric cell tests reveal that the K@NC@GDY-Al electrode exhibits an unprecedented cycle life of over 2400 h at a 40% depth of discharge. Even at an 80% depth of discharge, the cell can still sustain for 850 h. When paired with a potassium Prussian blue cathode, the thus-assembled full cell demonstrates comparable capacity and rate performance with state-of-the-art PMBs |
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| Beschreibung: | Date Revised 21.07.2022 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.202202685 |