A Stacked Plasmonic Metamaterial with Strong Localized Electric Field Enables Highly Efficient Broadband Light-Driven CO2 Hydrogenation

A Stacked Plasmonic Metamaterial with Strong Localized Electric Field Enables Highly Efficient Broadband Light-Driven CO2 Hydrogenation

© 2022 Wiley-VCH GmbH.

Détails bibliographiques
Publié dans:Advanced materials (Deerfield Beach, Fla.). - 1998. - 34(2022), 28 vom: 01. Juli, Seite e2202367
Auteur principal: Shao, Tianyi (Auteur)
Autres auteurs: Wang, Xiaonong, Dong, Hanxiao, Liu, Shengkun, Duan, Delong, Li, Yaping, Song, Pin, Jiang, Huijun, Hou, Zhonghuai, Gao, Chao, Xiong, Yujie
Format: Article en ligne
Langue:English
Publié: 2022
Accès à la collection:Advanced materials (Deerfield Beach, Fla.)
Sujets:Journal Article CO2 hydrogenation broadband light absorption light-driven catalysts localized electric field photothermal catalysis plasmonic metamaterials
LEADER 01000caa a22002652c 4500
001 NLM340506237
003 DE-627
005 20250303080337.0
007 cr uuu---uuuuu
008 231226s2022 xx |||||o 00| ||eng c
024 7 |a 10.1002/adma.202202367  |2 doi 
028 5 2 |a pubmed25n1134.xml 
035 |a (DE-627)NLM340506237 
035 |a (NLM)35522089 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Shao, Tianyi  |e verfasserin  |4 aut 
245 1 2 |a A Stacked Plasmonic Metamaterial with Strong Localized Electric Field Enables Highly Efficient Broadband Light-Driven CO2 Hydrogenation 
264 1 |c 2022 
336 |a Text  |b txt  |2 rdacontent 
337 |a ƒaComputermedien  |b c  |2 rdamedia 
338 |a ƒa Online-Ressource  |b cr  |2 rdacarrier 
500 |a Date Revised 14.07.2022 
500 |a published: Print-Electronic 
500 |a Citation Status PubMed-not-MEDLINE 
520 |a © 2022 Wiley-VCH GmbH. 
520 |a Light utilization largely governs the performance of CO2 photoconversion, whereas most of the materials that are implemented in such an application are restricted in a narrow spectral absorption range. Plasmonic metamaterials with a designable regular pattern and facile tunability are excellent candidates for maximizing light absorption to generate substantial hot electrons and thermal energy. Herein, a concept of coupling a Au-based stacked plasmonic metamaterial with single Cu atoms in alloy, as light absorber and catalytic sites, respectively, is reported for gas-phase light-driven catalytic CO2 hydrogenation. The metamaterial structure works in a broad spectral range (370-1040 nm) to generate high surface temperature for photothermal catalysis, and also induces strong localized electric field in favor of transfer of hot electrons and reduced energy barrier in CO2 hydrogenation. This work unravels the significant role of a strong localized electric field in photothermal catalysis and demonstrates a scalable fabrication approach to light-driven catalysts based on plasmonic metamaterials 
650 4 |a Journal Article 
650 4 |a CO2 hydrogenation 
650 4 |a broadband light absorption 
650 4 |a light-driven catalysts 
650 4 |a localized electric field 
650 4 |a photothermal catalysis 
650 4 |a plasmonic metamaterials 
700 1 |a Wang, Xiaonong  |e verfasserin  |4 aut 
700 1 |a Dong, Hanxiao  |e verfasserin  |4 aut 
700 1 |a Liu, Shengkun  |e verfasserin  |4 aut 
700 1 |a Duan, Delong  |e verfasserin  |4 aut 
700 1 |a Li, Yaping  |e verfasserin  |4 aut 
700 1 |a Song, Pin  |e verfasserin  |4 aut 
700 1 |a Jiang, Huijun  |e verfasserin  |4 aut 
700 1 |a Hou, Zhonghuai  |e verfasserin  |4 aut 
700 1 |a Gao, Chao  |e verfasserin  |4 aut 
700 1 |a Xiong, Yujie  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Advanced materials (Deerfield Beach, Fla.)  |d 1998  |g 34(2022), 28 vom: 01. Juli, Seite e2202367  |w (DE-627)NLM098206397  |x 1521-4095  |7 nnas 
773 1 8 |g volume:34  |g year:2022  |g number:28  |g day:01  |g month:07  |g pages:e2202367 
856 4 0 |u http://dx.doi.org/10.1002/adma.202202367  |3 Volltext 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_350 
951 |a AR 
952 |d 34  |j 2022  |e 28  |b 01  |c 07  |h e2202367