2D-Topology-Seeded Graphitization for Highly Thermally Conductive Carbon Fibers

2D-Topology-Seeded Graphitization for Highly Thermally Conductive Carbon Fibers

© 2022 Wiley-VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 34(2022), 28 vom: 05. Juli, Seite e2201867
1. Verfasser: Ming, Xin (VerfasserIn)
Weitere Verfasser: Wei, Anran, Liu, Yingjun, Peng, Li, Li, Peng, Wang, Jiaqing, Liu, Senping, Fang, Wenzhang, Wang, Ziqiu, Peng, Huanqin, Lin, Jiahao, Huang, Haoguang, Han, Zhanpo, Luo, Shiyu, Cao, Min, Wang, Bo, Liu, Zheng, Guo, Fenglin, Xu, Zhen, Gao, Chao
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2022
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article 2D seeds carbon fibers graphene oxide high thermal conductivity topology-graphitization
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520 |a Highly thermally conductive carbon fibers (CFs) have become an important material to meet the increasing demand for efficient heat dissipation. To date, high thermal conductivity has been only achieved in specific pitch-based CFs with high crystallinity. However, obtaining high graphitic crystallinity and high thermal conductivity beyond pitch-CFs remains a grand challenge. Here, a 2D-topology-seeded graphitization method is presented to mediate the topological incompatibility in graphitization by seeding 2D graphene oxide (GO) sheets into the polyacrylonitrile (PAN) precursor. Strong mechanical strength and high thermal conductivity up to 850 W m- 1 K-1 are simultaneously realized, which are one order of magnitude higher in conductivity than commercial PAN-based CFs. The self-oxidation and seeded graphitization effect generate large crystallite size and high orientation to far exceed those of conventional CFs. Topologically seeded graphitization, verified in experiments and simulations, allows conversion of the non-graphitizable into graphitizable materials by incorporating 2D seeds. This method extends the preparation of highly thermally conductive CFs, which has great potential for lightweight thermal-management materials 
650 4 |a Journal Article 
650 4 |a 2D seeds 
650 4 |a carbon fibers 
650 4 |a graphene oxide 
650 4 |a high thermal conductivity 
650 4 |a topology-graphitization 
700 1 |a Wei, Anran  |e verfasserin  |4 aut 
700 1 |a Liu, Yingjun  |e verfasserin  |4 aut 
700 1 |a Peng, Li  |e verfasserin  |4 aut 
700 1 |a Li, Peng  |e verfasserin  |4 aut 
700 1 |a Wang, Jiaqing  |e verfasserin  |4 aut 
700 1 |a Liu, Senping  |e verfasserin  |4 aut 
700 1 |a Fang, Wenzhang  |e verfasserin  |4 aut 
700 1 |a Wang, Ziqiu  |e verfasserin  |4 aut 
700 1 |a Peng, Huanqin  |e verfasserin  |4 aut 
700 1 |a Lin, Jiahao  |e verfasserin  |4 aut 
700 1 |a Huang, Haoguang  |e verfasserin  |4 aut 
700 1 |a Han, Zhanpo  |e verfasserin  |4 aut 
700 1 |a Luo, Shiyu  |e verfasserin  |4 aut 
700 1 |a Cao, Min  |e verfasserin  |4 aut 
700 1 |a Wang, Bo  |e verfasserin  |4 aut 
700 1 |a Liu, Zheng  |e verfasserin  |4 aut 
700 1 |a Guo, Fenglin  |e verfasserin  |4 aut 
700 1 |a Xu, Zhen  |e verfasserin  |4 aut 
700 1 |a Gao, Chao  |e verfasserin  |4 aut 
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773 1 8 |g volume:34  |g year:2022  |g number:28  |g day:05  |g month:07  |g pages:e2201867 
856 4 0 |u http://dx.doi.org/10.1002/adma.202201867  |3 Volltext 
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