Structural Evolution of a Polystyrene-Block-Poly(Ethylene Oxide) Block Copolymer in Tetrahydrofuran/Water Cosolvents
This study aims to quantitatively investigate the effect of water content on the self-assembly behavior of polystyrene-block-poly(ethylene oxide) (PS-b-PEO) in tetrahydrofuran/water cosolvents by small-angle X-ray scattering. PS-b-PEO chains preferentially form fractal aggregates at a dilute concent...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 38(2022), 19 vom: 17. Mai, Seite 5987-5995 |
|---|---|
| 1. Verfasser: | |
| Weitere Verfasser: | , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2022
|
| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article Research Support, Non-U.S. Gov't Furans Micelles Polymers Polystyrenes Water 059QF0KO0R Ethylene Oxide JJH7GNN18P |
| Zusammenfassung: | This study aims to quantitatively investigate the effect of water content on the self-assembly behavior of polystyrene-block-poly(ethylene oxide) (PS-b-PEO) in tetrahydrofuran/water cosolvents by small-angle X-ray scattering. PS-b-PEO chains preferentially form fractal aggregates at a dilute concentration in neat tetrahydrofuran (THF). By adding a small amount of water into THF, PS-b-PEO forms gelled networks. The gelled networks have correlated inhomogeneities, which were generated through mesophase separation. These gelled networks are not present when PS-b-PEO is dissolved in THF/methanol and THF/ethanol cosolvents. The substitution of water with 12 M HCl reduces the viscosity of the gelled networks. Those results indicate that the gelled networks of PS-b-PEO need hydrogen bonds formed from surrounding water molecules to be bridging agents, which connect different PEO block chains together. Upon increasing the water content in THF/water cosolvents, dispersed micelles with a core-shell conformation or aggregated micelles preferentially coexist with fractal aggregates |
|---|---|
| Beschreibung: | Date Completed 19.05.2022 Date Revised 20.07.2022 published: Print-Electronic Citation Status MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/acs.langmuir.2c00041 |