Tuning the Charge of Sliding Water Drops

When a water drop slides over a hydrophobic surface, it usually acquires a positive charge and deposits the negative countercharge on the surface. Although the electrification of solid surfaces induced after contact with a liquid is intensively studied, the actual mechanisms of charge separation, so...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 38(2022), 19 vom: 17. Mai, Seite 6224-6230
1. Verfasser: Wong, William S Y (VerfasserIn)
Weitere Verfasser: Bista, Pravash, Li, Xiaomei, Veith, Lothar, Sharifi-Aghili, Azadeh, Weber, Stefan A L, Butt, Hans-Jürgen
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2022
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a When a water drop slides over a hydrophobic surface, it usually acquires a positive charge and deposits the negative countercharge on the surface. Although the electrification of solid surfaces induced after contact with a liquid is intensively studied, the actual mechanisms of charge separation, so-termed slide electrification, are still unclear. Here, slide electrification is studied by measuring the charge of a series of water drops sliding down inclined glass plates. The glass was coated with hydrophobic (hydrocarbon/fluorocarbon) and amine-terminated silanes. On hydrophobic surfaces, drops charge positively while the surfaces charge negatively. Hydrophobic surfaces coated with a mono-amine (3-aminopropyltriethyoxysilane) lead to negatively charged drops and positively charged surfaces. When coated with a multiamine (N-(3-trimethoxysilylpropyl)diethylenetriamine), a gradual transition from positively to negatively charged drops is observed. We attribute this tunable drop charging to surface-directed ion transfer. Some of the protons accepted by the amine-functionalized surfaces (-NH2 with H+ acceptor) remain on the surface even after drop departure. These findings demonstrate the facile tunability of surface-controlled slide electrification 
650 4 |a Journal Article 
700 1 |a Bista, Pravash  |e verfasserin  |4 aut 
700 1 |a Li, Xiaomei  |e verfasserin  |4 aut 
700 1 |a Veith, Lothar  |e verfasserin  |4 aut 
700 1 |a Sharifi-Aghili, Azadeh  |e verfasserin  |4 aut 
700 1 |a Weber, Stefan A L  |e verfasserin  |4 aut 
700 1 |a Butt, Hans-Jürgen  |e verfasserin  |4 aut 
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