Ultrasonication-assisted synthesis of CN-TiO2 and its photocatalytic degradation of diclofenac under visible light irradiation
In this study, CN codoped TiO2 nanoparticles (CN-TiO2) were fabricated by solvothermal and low temperature calcination methods with the aid of ultrasonication. According to the number of ultrasonic treatments used in the preparation process, the samples were named NN, YN, NY and YY. The characterist...
| Veröffentlicht in: | Environmental technology. - 1993. - 44(2023), 24 vom: 03. Okt., Seite 3667-3675 |
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| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2023
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| Zugriff auf das übergeordnete Werk: | Environmental technology |
| Schlagworte: | Journal Article CN-codoped TiO2 diclofenac photocatalysis ultrasonication visible light titanium dioxide 15FIX9V2JP Diclofenac 144O8QL0L1 mehr... |
| Zusammenfassung: | In this study, CN codoped TiO2 nanoparticles (CN-TiO2) were fabricated by solvothermal and low temperature calcination methods with the aid of ultrasonication. According to the number of ultrasonic treatments used in the preparation process, the samples were named NN, YN, NY and YY. The characteristics of transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and ultraviolet-visible spectroscopy (UV-vis) were employed to analyse the effect of the ultrasonic treatment step in the synthetic process. The results showed that ultrasonication can increase the CN content in TiO2, reduce the band gap energy, and improve the catalytic performance of the CN-TiO2, and the effect of secondary ultrasound is particularly obvious. The YY obtained by two-step ultrasonication with the lowest band gap energy of 3.07 eV. The photocatalytic activity of the CN-TiO2 was evaluated using the degradation of diclofenac (DCF) under visible light irradiation (white LED strips with an emission wavelength of 450 nm). It was observed that the YY exhibited significantly superior DCF degradation activity. When using 0.4 g L-1 of YY, an excellent DCF degradation of 97% could be reached, which is 1.4 times that of NN (without ultrasonication). Moreover, YY had good visible light photocatalytic activity, and the degradation efficiency of YY for DCF under visible light was comparable to that of a xenon lamp. Therefore, ultrasonication played a critical role in the enhancement of photocatalytic activity during the synthesis of CN-TiO2 |
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| Beschreibung: | Date Completed 11.09.2023 Date Revised 11.09.2023 published: Print-Electronic Citation Status MEDLINE |
| ISSN: | 1479-487X |
| DOI: | 10.1080/09593330.2022.2068382 |